Acoustically resistive supported membrane assemblies including at least one support structure

ABSTRACT

Water impermeable, air permeable membrane assemblies are described herein. In some embodiments, the assemblies include a polymer membrane and at least one support structure. Certain assemblies are configured to provide an acoustic impedance having phase angle of +45 degrees to −45 over a frequency range of 50 to 20,000 Hz.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit of U.S. Provisional Application No. 63/060,260, entitled “ACOUSTICALLY RESISTIVE SUPPORTED MEMBRANE ASSEMBLIES INCLUDING AT LEAST ONE SUPPORT STRUCTURE,” filed on Aug. 3, 2020, the entirety of which is hereby incorporated by reference.

FIELD

The field of the present disclosure relates to acoustic membrane assemblies.

BACKGROUND

Acoustic membrane assemblies can allow sound to propagate through and past a membrane and to and from a device. Acoustic membranes can also prevent ingress of water, dust and other contaminants. There is an ongoing need in the art for improved acoustic membranes.

SUMMARY

Covered embodiments are defined by the claims, not this summary. This summary is a high-level overview of various aspects and introduces some of the concepts that are further described in the Detailed Description section below. This summary is not intended to identify key or essential features of the claimed subject matter, nor is it intended to be used in isolation to determine the scope of the claimed subject matter. The subject matter should be understood by reference to appropriate portions of the entire specification, any or all drawings, and each claim.

The present disclosure relates to an assembly comprising a polymer membrane and at least one support structure.

In some embodiments, the at least one support structure is in contact with the polymer membrane.

In some embodiments, the assembly has an airflow resistance of from 100 to 50,000 Rayls.

In some embodiments, the assembly has an effective stiffness from 0.0002 Pa/nm to 3,000 Pa/nm when measured using the Vibrational Displacement Test (“VDT”).

In some embodiments, the assembly has an acoustic impedance with a phase angle of +45 degrees to −45 degrees over a frequency range of 50 to 20,000 Hz as measured by the Impedance Tube Transfer Matrix Test (“ITTMT”).

In some embodiments, the assembly exhibits a transmission loss that does not vary by more than 1.5 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”).

In some embodiments, the assembly has a water entry pressure (“WEP”) ranging from 10 psi to 350 psi measured in accordance with the Capillary Piston Test (“CPT”).

In some embodiments, the assembly exhibits a transmission loss of from 3 dB to 48 dB when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”) over the frequency range of 50 to 20,000 Hz.

In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 300 microns.

In some embodiments, the polymer membrane comprises a plurality of pores with different pore sizes.

In some embodiments, the plurality of pores has a maximum pore size ranging from 0.1 to 30 microns.

In some embodiments, the polymer membrane has a bubble point ranging from 0.4 psi to 120 psi.

In some embodiments, the polymer membrane comprises expanded polytetrafluoroethylene (ePTFE).

In some embodiments, the polymer membrane has a Young's Modulus ranging from 1 MPa to 1000 MPa.

In some embodiments, the at least one support structure is at least one second polymer membrane.

In some embodiments, the support structure is a network of particles.

In some embodiments, the at least one support structure has a thickness of 10 to 1000 microns.

In some embodiments, the at least one support structure has an effective open area of from 5% to 98%.

In some embodiments, the assembly comprises a single support structure.

In some embodiments, the assembly comprises at least two support structures.

In some embodiments, the assembly comprises a first support structure and a second support structure, and the polymer membrane is sandwiched between the first support structure and the second support structure.

In some embodiments, the first and second support structures comprise the same material.

In some embodiments, the first and second support structures comprise a different material.

In some embodiments, there is an adhesive between the polymer membrane and the at least one support structure.

In some embodiments, the at least one support structure is at least one support layer.

In some embodiments, the at least one support layer comprises fiberglass.

In some embodiments, the at least one support layer comprises a metal.

In some embodiments, the metal is brass.

In some embodiments, the one or more support layers comprises a mesh.

In some embodiments, the mesh is woven polyethylene terephthalate (PET) mesh.

In some embodiments, the mesh is extruded plastic non-woven mesh.

In some embodiments, the assembly is included in an acoustic device. In some embodiments, the acoustic device includes a speaker, a receiver, or any combination thereof.

BRIEF DESCRIPTION OF THE DRAWINGS

Some embodiments of the disclosure are herein described, by way of example only, with reference to the accompanying drawings. With specific reference now to the drawings in detail, the embodiments shown are by way of example and for purposes of illustrative discussion of embodiments of the disclosure. In this regard, the description taken with the drawings makes apparent to those skilled in the art how embodiments of the disclosure may be practiced.

FIG. 1 depicts an exemplary assembly in accordance with the present disclosure and having a single support structure in the form of a single support layer.

FIG. 2 depicts an additional exemplary assembly in accordance with the present disclosure having two support structures in the form of two support layers.

FIG. 3 is a schematic illustration of an exemplary 4-microphone impedance tube used for transmission loss and phase testing of certain assemblies described herein, as described in the Test Procedures section.

FIG. 4 depicts exemplary plates used for transmission loss testing with compression, as described in the Test Procedures section.

FIGS. 5 and 6 depict micrographs used to measure the % contact of exemplary assemblies.

FIGS. 7-18 depict exemplary acoustic characteristics of exemplary assemblies.

FIGS. 19-29 depict exemplary acoustic characteristics of exemplary assemblies before and after air pressure test.

FIG. 30 depicts exemplary acoustic characteristics of exemplary assemblies under compression force.

FIGS. 31-32 depict non-limiting examples of consistency of acoustic characteristics of exemplary assemblies.

FIG. 33 depicts exemplary tunable acoustic characteristics of non-limiting assemblies.

FIG. 34 depicts an exemplary test-set up for assembly having a single support structure.

FIG. 35 is a 2-D optical profilometry micrograph showing the top-most 20 μm of an exemplary support structure.

FIGS. 36-38 are exemplary scanning electron micrographs (SEMs) showing microstructures of exemplary support structures, some of which are bonded to a polymer membrane.

FIGS. 39-41 depict additional non-limiting examples of acoustic characteristics of exemplary assemblies.

DETAILED DESCRIPTION

Among those benefits and improvements that have been disclosed, other objects and advantages of this disclosure will become apparent from the following description taken in conjunction with the accompanying figures. Detailed embodiments of the present disclosure are disclosed herein; however, the disclosed embodiments are merely illustrative of the disclosure that may be embodied in various forms. In addition, each of the examples given regarding the various embodiments of the disclosure are intended to be illustrative, and not restrictive.

Throughout the specification and claims, the following terms take the meanings explicitly associated herein, unless the context clearly dictates otherwise. The phrases “in one embodiment,” “in an embodiment,” and “in some embodiments” as used herein do not necessarily refer to the same embodiment(s), though it may. Furthermore, the phrases “in another embodiment” and “in some other embodiments” as used herein do not necessarily refer to a different embodiment, although it may. All embodiments of the disclosure are intended to be combinable without departing from the scope or spirit of the disclosure.

As used herein, the term “based on” is not exclusive and allows for being based on additional factors not described, unless the context clearly dictates otherwise. In addition, throughout the specification, the meaning of “a,” “an,” and “the” include plural references. The meaning of “in” includes “in” and “on.”

All prior patents, publications, and test methods referenced herein are incorporated by reference in their entireties.

Some embodiments of the present disclosure are directed to a predominantly resistive supported acoustic membrane assembly that comprises a polymer membrane and at least one support structure.

In some embodiments, the polymer membrane in the assembly includes a plurality of pores. In some embodiments, the plurality of pores can have a maximum pore size. As used herein, “maximum pore size,” is the size of the largest pore of the plurality of pores.

In some embodiments, the plurality of pores can have a maximum pore size of 0.1 to 30 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.3 to 30 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.5 to 30 microns. In some embodiments, the plurality of pores can have a maximum pore size of 10 to 30 microns. In some embodiments, the plurality of pores can have a maximum pore size of 20 to 30 microns. In some embodiments, the plurality of pores can have a maximum pore size of 25 to 30 microns.

In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.4 to 4 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.8 to 2 microns. In some embodiments, the plurality of pores can have a maximum pore size of 1 to 1.6 microns.

In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 4 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 2 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 1.6 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 1 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 0.8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.2 to 0.4 microns.

In some embodiments, the plurality of pores can have a maximum pore size of 0.4 to 8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 0.8 to 8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 1 to 8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 1.6 to 8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 2 to 8 microns. In some embodiments, the plurality of pores can have a maximum pore size of 4 to 8 microns.

In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.12 microns to 65 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.24 microns to 30 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.5 microns to 15 microns. In some embodiments, the polymer membrane has a thickness ranging from 1 micron to 8 microns. In some embodiments, the polymer membrane has a thickness ranging from 2 microns to 4 microns.

In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 300 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.061 microns to 126 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 150 microns.

In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 150 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 100 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 50 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 25 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 10 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 5 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 2.5 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 1 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.025 microns to 0.3 microns.

In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 65 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 30 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 15 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 8 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 micron to 4 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 2 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 1 micron. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 0.5 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 0.24 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.06 microns to 0.12 microns.

In some embodiments, the polymer membrane has a thickness ranging from 0.12 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.24 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 0.5 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 1 micron to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 2 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 4 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 8 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 15 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 30 microns to 130 microns. In some embodiments, the polymer membrane has a thickness ranging from 65 microns to 130 microns.

In some embodiments, the polymer membrane comprises at least one of: polyolefins, polyurethanes, polyesters, polyamides, polyketones, polysulfones, or polycarbonates. In some embodiments, the polymer membrane can comprise a fluoropolymer. In some embodiments, the fluoropolymer comprises one or more of PVDF, polyvinylidene diflouride, poly(tetrafluoroethylene-co-hexafluoropropylene (FEP), poly(ethylene-alt-tetrafluoroethylene) (ETFE), polychlorotrifluoroethylene (PCTFE), poly(tetrafluoroethylene-co-perfluoropropyl vinyl ether) (PFA), poly(vinylidene fluoride-co-hexafluoropropylene (PVDF-co-HFP), polyvinyl fluoride (PVF), or any combination thereof.

In some embodiments, the fluoropolymer is polytetrafluoroethylene (PTFE). In some embodiments, the PTFE is expanded polytetrafluoroethylene (ePTFE). In some embodiments, the ePTFE comprises a microstructure, characterized by nodes interconnected by fibrils, as one of the ePTFE compositions disclosed in U.S. Pat. No. 3,953,566 to Gore or U.S. Pat. No. 4,902,423 to Bacino.

In some embodiments, the polymer membrane has an air flow resistance ranging from 75 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 100 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 25,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 800 to 12,500 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 1600 to 6000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 3000 to 4000 Rayls.

In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 25,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 12,500 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 6000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 4000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 3000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 1600 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 200 to 800 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 400 to 800 Rayls.

In some embodiments, the polymer membrane has an air flow resistance ranging from 400 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 800 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 1600 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 3000 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 6000 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 12,500 to 50,000 Rayls. In some embodiments, the polymer membrane has an air flow resistance ranging from 25,000 to 50,000 Rayls.

In some embodiments, the polymer membrane has a Young's Modulus ranging from 1 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 2 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 5 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 10 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 25 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 50 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 100 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 250 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 500 MPa to 1000 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 750 MPa to 1000 MPa.

In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 8 MPa to 180 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 16 MPa to 90 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 32 MPa to 45 MPa.

In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 180 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 90 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 45 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 32 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 16 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 4 MPa to 8 MPa.

In some embodiments, the polymer membrane has a Young's Modulus ranging from 8 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 16 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 32 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 45 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 90 MPa to 360 MPa. In some embodiments, the polymer membrane has a Young's Modulus ranging from 180 MPa to 360 MPa.

In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 120 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 100 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 80 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 60 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 40 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 20 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 10 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 5 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 2 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 1 psi. In some embodiments, the polymer membrane has a bubble point ranging from 0.4 to 0.5 psi.

In some embodiments, the polymer membrane has a bubble point ranging from 1.5 to 56 psi. In some embodiments, the polymer membrane has a bubble point ranging from 1.5 to 60 psi. In some embodiments, the polymer membrane has a bubble point ranging from 3 to 28 psi. In some embodiments, the polymer membrane has a bubble point ranging from 6 to 16 psi.

In some embodiments, the polymer membrane has a bubble point ranging from 1.5 to 28 psi. In some embodiments, the polymer membrane has a bubble point ranging from 1.5 to 14 psi. In some embodiments, the polymer membrane has a bubble point ranging from 1.5 to 7 psi. In some embodiments, the polymer membrane has a bubble point ranging from 1.5 to 3.5 psi.

In some embodiments, the polymer membrane has a bubble point ranging from 3 to 56 psi. In some embodiments, the polymer membrane has a bubble point ranging from 3 to 28 psi. In some embodiments, the polymer membrane has a bubble point ranging from 3 to 14 psi. In some embodiments, the polymer membrane has a bubble point ranging from 3 to 7 psi.

In some embodiments, the polymer membrane can have a homogeneous pore size distribution. A homogenous pore size distribution is where the pore size distribution remains the same as a function of thickness within the membrane. an inhomogeneous pore size distribution is where the pore size distribution changes as a function of thickness within the membrane. In some embodiments, the pore size distribution is homogeneous. In other embodiments, the pore size distribution is inhomogeneous.

In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.05 to 5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.1 to 2 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.2 to 1 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.4 to 1 g/m².

In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 2 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 1 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 0.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 0.4 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 0.2 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.01 to 0.05 g/m².

In some embodiments, the polymer membrane has a mass per unit area ranging from 0.05 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.1 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.2 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.4 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 0.5 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 1 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 2 to 7.5 g/m². In some embodiments, the polymer membrane has a mass per unit area ranging from 5 to 7.5 g/m².

In some embodiments, the polymer membrane exhibits a Water Entry Pressure (“WEP”) of 0.5 to 450 psi. In some embodiments, the polymer membrane exhibits a WEP of 0.5 psi to 200 psi. In some embodiments, the polymer membrane exhibits a WEP of 1 psi to 150 psi. In some embodiments, the polymer membrane exhibits a WEP of 1.0 psi to 100 psi. In some embodiments, the polymer membrane exhibits a WEP of 1 psi to 50 psi. In some embodiments, the polymer membrane exhibits a WEP of 25 psi to 150.0 psi. In some embodiments, the polymer membrane exhibits a WEP of 50.0 psi to 150.0 psi. In some embodiments, the polymer membrane exhibits a WEP of 1.0 psi to 110.8 psi.

In some embodiments, the polymer membrane exhibits a Water Entry Pressure (“WEP”) of 1.4 to 432 psi. In some embodiments, the polymer membrane exhibits a Water Entry Pressure (“WEP”) of 0.95 to 432 psi. In some embodiments, the polymer membrane exhibits a Water Entry Pressure (“WEP”) of 0.95 to 111 psi.

In some embodiments, at least a portion of the at least one support structure comprises a portion that is in contact with the polymer membrane. “Contact” includes but does not limit to direct physical contact and bonding through adhesive, lamination, and static. Contact is measured using the procedure defined herein in the Test Procedures section.

The % contact between the polymer membrane and support structure can be determined using the method described in the Test Procedures section.

In some embodiments, 0.1% to 99.6% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 1% to 50% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 2% to 25% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 4% to 12% of the at least one support structure is in contact with the polymer membrane.

In some embodiments, 0.5% to 80% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 1% to 40% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 2% to 20% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 5% to 10% of the at least one support structure is in contact with the polymer membrane.

In some embodiments, 12% to 91% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 24% to 76% of the at least one support structure is in contact with the polymer membrane. In some embodiments, 36% to 48% of the at least one support structure is in contact with the polymer membrane.

The “% open area” is the portion of the at least one support structure that does not contact the polymer membrane. In some embodiments, the % open area of the at least one support structure ranges from 5% to 98%. In some embodiments, the % open area of the at least one support structure ranges from 10% to 49%. In some embodiments, the % open area of the at least one support structure ranges from 20% to 24%. In some embodiments, the % open area of the at least one support structure ranges from 12% to 40%. In some embodiments, the % open area of the at least one support structure ranges from 24% to 80%.

In some embodiments, the at least one support structure has a thickness of 1 to 1000 microns. In some embodiments, the at least one support structure has a thickness of 2 to 500 microns. In some embodiments, the at least one support structure has a thickness of 4 to 250 microns. In some embodiments, the at least one support structure has a thickness of 8 to 125 microns. In some embodiments, the at least one support structure has a thickness of 16 to 75 microns. In some embodiments, the at least one support structure has a thickness of 32 to 50 microns.

In some embodiments, the at least one support structure has a thickness of 10 to 1000 microns. In some embodiments, the at least one support structure has a thickness of 30 to 600 microns. In some embodiments, the at least one support structure has a thickness of 60 to 300 microns. In some embodiments, the at least one support structure has a thickness of 80 to 200 microns. In some embodiments, the at least one support structure has a thickness of 90 to 100 microns.

In some embodiments, the at least one support structure has a thickness of 40 to 200 microns. In some embodiments, the at least one support structure has a thickness of 40 to 300 microns. In some embodiments, the at least one support structure has a thickness of 40 to 100 microns. In some embodiments, the at least one support structure has a thickness of 40 to 90 microns. In some embodiments, the at least one support structure has a thickness of 40 to 80 microns. In some embodiments, the at least one support structure has a thickness of 40 to 60 microns.

In some embodiments, the at least one support structure has a thickness of 40 to 410 microns. In some embodiments, the at least one support structure has a thickness of 60 to 410 microns. In some embodiments, the at least one support structure has a thickness of 80 to 410 microns. In some embodiments, the at least one support structure has a thickness of 90 to 410 microns. In some embodiments, the at least one support structure has a thickness of 100 to 410 microns. In some embodiments, the at least one support structure has a thickness of 200 to 410 microns. In some embodiments, the at least one support structure has a thickness of 300 to 410 microns. In some embodiments, the at least one support structure has a thickness of 20 to 750 microns.

In some embodiments, the at least one support structure has an air flow resistance ranging from 10 to 5000 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 20 to 4000 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 20 to 3000 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 3000 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 80 to 2500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 160 to 2000 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 300 to 1800 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 600 to 1600 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 800 to 1200 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 900 to 1000 Rayls.

In some embodiments, the at least one support structure has an air flow resistance ranging from 10 to 1500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 20 to 750 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 400 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 80 to 200 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 90 to 100 Rayls.

In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 1500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 43 to 1458 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 80 to 750 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 160 to 500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 250 to 320 Rayls.

In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 750 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 320 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 250 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 160 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 40 to 80 Rayls.

In some embodiments, the at least one support structure has an air flow resistance ranging from 80 to 1500 Rayls. In some embodiments, the at least one support layer has an air flow resistance ranging from 160 to 1500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 250 to 1500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 320 to 1500 Rayls. In some embodiments, the at least one support structure has an air flow resistance ranging from 750 to 1500 Rayls.

As used herein, “effective stiffness” is defined as the ratio between an applied force and the displacement that results from the applied force. Effective stiffness is measured herein using the Vibration Displacement Test (“VDT”).

In some embodiments, the at least one support structure has an effective stiffness of 0.01 Pa/nm to 15 Pa/nm. In some embodiments, the at least one support structure has an effective stiffness of 0.5 Pa/nm to 5 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 1 Pa/nm to 2 Pa/nm when measured using the VDT.

In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 0.1 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 0.5 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 1 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 2 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 5 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 15 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.05 Pa/nm to 25 Pa/nm when measured using the VDT.

In some embodiments, the at least one support structure has an effective stiffness of 0.1 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 0.5 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 1 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 2 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 5 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the at least one support structure has an effective stiffness of 15 Pa/nm to 25 Pa/nm when measured using the VDT.

In some embodiments, the at least one support structure has a mass per area of 0.1 g/m² to 500 g/m². In some embodiments, the at least one support structure has a mass per area of 1 g/m² to 500 g/m². In some embodiments, the at least one support structure has a mass per area of 10 g/m² to 500 g/m². In some embodiments, the at least one support structure has a mass per area of 100 g/m² to 500 g/m².

In some embodiments, the at least one support structure has a mass per area of 0.1 g/m² to 100 g/m². In some embodiments, the at least one support structure has a mass per area of 0.1 g/m² to 10 g/m². In some embodiments, the at least one support structure has a mass per area of 0.1 g/m² to 1 g/m².

In some embodiments, the at least one support structure has a mass per area of 1 g/m² to 100 g/m². In some embodiments, the at least one support structure has a mass per area of 1 g/m² to 10 g/m². In some embodiments, the at least one support structure has a mass per area of 10 g/m² to 100 g/m².

In some embodiments, the at least one support structure is bonded to the polymer membrane by one or more adhesives. In some embodiments, the adhesive comprises one or more high melt thermoplastics. In one embodiment, the high melt thermoplastic material may include poly(ethylene-co-tetrafluoroethylene-co-hexafluoropropylene (EFEP), tetrafluoroethylene hexafluoropropylene vinylidene fluoride (THV), poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP), perfluoroalkoxy (PFA), Ethylene tetrafluoroethylene (ETFE), PVC resins, nitrile rubber, or combinations thereof.

In some embodiments, the polymer membrane is laminated to the at least one support structure. In some embodiments the lamination is laser lamination. In some embodiments the lamination is thermal lamination. In some embodiments, the polymer membrane is sandwiched between one surface of a first support structure and one surface of a second support structure.

In some embodiments, the polymer membrane is mechanically attached to the at least one support structure. Examples of mechanical attachment include, but are not limited to, mechanical co-expansion, calendering, or any combination thereof.

In some embodiments, the support structure is deposited on the membrane. Examples of deposition methods include, but are not limited to, thermal deposition, vapor deposition, or any combination thereof.

In some embodiments, the polymer membrane of the assembly is a first polymer membrane and the at least one support structure is at least one second polymer membrane. In some embodiments the at least one second polymer membrane is the same as the first polymer membrane. In some embodiments, the at least one second polymer membrane is different from the first polymer membrane.

In some embodiments, the at least one second polymer membrane has a maximum pore size that is less than the maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is equal to the maximum pore size of the first polymer membrane.

In some embodiments, the at least one second polymer membrane has a maximum pore size that exceeds the maximum pore size of the first polymer membrane.

In some embodiments, the at least one second polymer membrane has a maximum pore size that is 1% to 1000% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 5% to 1000% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 10% to 1000% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 50% to 1000% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 100% to 1000% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 500% to 1000% larger than a maximum pore size of the first polymer membrane.

In some embodiments, the at least one second polymer membrane has a maximum pore size that is 1% to 500% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 1% to 100% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 1% to 50% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 1% to 10% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 1% to 5% larger than a maximum pore size of the first polymer membrane.

In some embodiments, the at least one second polymer membrane has a maximum pore size that is 5% to 500% larger than a maximum pore size of the first polymer membrane. In some embodiments, the at least one second polymer membrane has a maximum pore size that is 10% to 100% larger than a maximum pore size of the first polymer membrane.

In some embodiments, the at least one second polymer membrane comprises at least one of: polyolefins, polyurethanes, polyesters, polyamides, polyketones, polysulfones, or polycarbonates. In some embodiments, the polymer membrane can comprise a fluoropolymer. In some embodiments, the fluoropolymer comprises one or more of PVDF, polyvinylidene diflouride, poly(tetrafluoroethylene-co-hexafluoropropylene) (FEP), poly(ethylene-alt-tetrafluoroethylene) (ETFE), polychlorotrifluoroethylene (PCTFE), poly(tetrafluoroethylene-co-perfluoropropyl vinyl ether) (PFA), poly(vinylidene fluoride-co-hexafluoropropylene (PVDF-co-HFP), polyvinyl fluoride (PVDF), or any combination thereof.

In some embodiments, the fluoropolymer is polytetrafluoroethylene (PTFE). In some embodiments, the PTFE is expanded polytetrafluoroethylene (ePTFE). In some embodiments, the ePTFE comprises a microstructure, characterized by nodes interconnected by fibrils, as one of the ePTFE compositions disclosed in U.S. Pat. No. 3,953,566 to Gore or U.S. Pat. No. 4,902,423 to Bacino.

In some embodiments, the support structure comprises a network of particles.

In some embodiments, the particles of the network of particles may be polymeric particles, non-polymeric particles, or any combination thereof.

In some embodiments, the particles of the network of particles may include ethylene fluorinated ethylene propylene (EFEP) particles, perfluoroalkoxy alkane (PFA) particles, tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride terpolymer (THV) particles, polyvinylidene difluoride (PVDF) particles, chlorotrifluoroethylene (CTFE) particles, silica particles, carbon particles, polyphenylene sulfide (PPS) particles, polyimide particles, fluorinated ethylene propylene (FEP) particles, or any combination thereof.

In some embodiments, the particles of the network of particles are FEP particles.

In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 10 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 25 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 50 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 75 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 90 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 95 μm to 100 μm.

In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 95 μm. In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 90 μm. In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 75 μm. In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 50 μm. In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 25 μm. In some embodiments, each particle of the network of particles has a size ranging from 5 μm to 10 μm.

In some embodiments, each particle of the network of particles has a size ranging from 10 μm to 100 μm. In some embodiments, each particle of the network of particles has a size ranging from 25 μm to 90 μm. In some embodiments, each particle of the network of particles has a size ranging from 10 μm to 100 μm.

In some embodiments, the network of particles may be formed on the polymer membrane (so as to form an assembly), such as, but not limited by deposition of the particles, e.g., by any deposition method described herein.

In some embodiments, the network of particles is a coherent network of particles. As used herein, a “coherent network of particles” is a network of particles that is connected in such a way that the network of particles has a unitary structure. In some embodiments, the network of particles may be attached to the polymer membrane as a pre-formed unitary structure (i.e., as a coherent network and not as individual particles).

In some embodiments, the network of particles is an irregular network of particles. As used herein, an irregular network of particles is a network of particles where each individual particle does not necessarily have the same geometry or the same particle type.

In some embodiments, the network of particles is a coherent irregular network of particles. As used herein, a “coherent irregular network of particles” is a network of particles that is both a coherent network of particles and an irregular network of particles, as described herein.

In some embodiments, the at least one support structure is at least one support layer.

In some embodiments, the at least one support layer comprises a plurality of openings. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 1 to 500 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 5 to 500 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 2 to 250 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 4 to 125 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 8 to 75 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 16 to 50 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 25 to 32 microns.

In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 10 to 350 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 20 to 180 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 40 to 90 microns.

In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 20 to 40 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 20 to 80 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 20 to 90 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 20 to 180 microns.

In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 40 to 350 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 80 to 350 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 90 to 350 microns. In some embodiments, the largest dimension of a single opening of the plurality of openings of the at least one support layer ranges from 180 to 350 microns.

In some embodiments, the at least one support layer comprises at least one metal. In some embodiments, the at least one support layer comprises at least one polymer. In some embodiments, the at least one support layer comprises fiberglass. In some embodiments, the at least one support layer comprises at least one or more metals, one or more polymers, or fiberglass. In some embodiments, there is a single support layer. In some embodiments there are at least two support layers. In some embodiments each support layer is the same material. In some embodiments each support layer is a different material. In some embodiments, the first support layer type is a first metal and the second support layer type is a second metal. In some embodiments, the first support layer type is a metal and the second support layer type is a polymer or fiberglass. In some embodiments the first support layer type is a first polymer and the second support layer type is a second polymer. In some embodiments, the first support layer and the second support layers are both fiberglass.

In some embodiments the at least one metal comprises one or more of zinc, nickel, chromium, vanadium, molybdenum, manganese, copper, iron, aluminum, titanium, combinations and alloys thereof. In some embodiments, the metal comprises an alloy such as carbon steel, stainless steel, bronze, brass, combinations thereof, or composite alloys thereof.

In some embodiments, the at least one polymer of the at least one support layer is in the form of a woven or nonwoven material. In some embodiments, the at least one polymer of the support layer comprises one or more of: extruded plastic, polyethylene terephthalate (PET), polyphenylene sulfide (PPS), polybutylene terephthalate (PBT), polyether ether ketone (PEEK); polypthalamides (PPA), acetal homopolymers; polyethylene terephthalate (PET), one or more thermoset epoxies, or one or more thermoset elastomers. In some embodiments, the support layer might include multiple components with different melting temperatures.

In some embodiments, the assembly has an effective stiffness of 0.0002 Pa/nm to 3000 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.0002 Pa/nm to 1000 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.0002 Pa/nm to 100 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.198 Pa/nm to 29.8 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.001 Pa/nm to 500 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.01 Pa/nm to 250 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.05 Pa/nm to 100 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.1 Pa/nm to 50 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 1 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 5 Pa/nm to 10 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.0002 Pa/nm to 100 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.0006 Pa/nm to 29.8 Pa/nm when measured using the VDT.

In some embodiments, the assembly has an effective stiffness of 0.0005 Pa/nm to 30 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.005 Pa/nm to 25 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.05 Pa/nm to 20 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.1 Pa/nm to 15 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 1 Pa/nm to 10 Pa/nm when measured using the VDT.

In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 32 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.3 Pa/nm to 16 Pa/nm. In some embodiments, the assembly has an effective stiffness of 0.6 Pa/nm to 8 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 1 Pa/nm to 4 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 2 Pa/nm to 3 Pa/nm when measured using the VDT.

In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 16 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 8 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 4 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 3 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 2 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 1 Pa/nm when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 0.6 Pa/nm. when measured using the VDT. In some embodiments, the assembly has an effective stiffness of 0.15 Pa/nm to 0.3 Pa/nm when measured using the VDT.

In some embodiments, the assembly has an air flow resistance ranging from 100 to 800,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 200 to 400,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 400 to 200,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 800 to 100,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 1600 to 50,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 3200 to 25,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 6400 to 10,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 8000 to 9000 Rayls.

In some embodiments, the assembly has an air flow resistance ranging from 100 to 50,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 200 to 20,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 400 to 10,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 800 to 5000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 1600 to 2500 Rayls.

In some embodiments, the assembly has an air flow resistance ranging from 100 to 20,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 10,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 5000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 2500 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 1600 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 800 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 400 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100 to 200 Rayls.

In some embodiments, the assembly has an air flow resistance ranging from 10,000 to 800,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 20,000 to 400,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 40,000 to 200,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 80,000 to 100,000 Rayls.

In some embodiments, the assembly has an air flow resistance ranging from 50,000 to 800,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 100,000 to 800,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 200,000 to 800,000 Rayls. In some embodiments, the assembly has an air flow resistance ranging from 400,000 to 800,000 Rayls.

In some embodiments, the predominantly resistive acoustic behavior is a result of the effective stiffness (as described herein) of the at least one support layer of the assembly. The phase angle of the acoustic impedance of the assembly is measured herein by the Impedance Tube Transfer Matrix Test (“ITTMT”) that is described in Test Procedures section.

As used herein, the term “predominantly resistive” means that the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +30 degrees to −30 degrees over a frequency range of 500 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +15 degrees to −15 degrees over a frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +5 degrees to −5 degrees over a frequency range of 500 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +1 degree to −1 degree over a frequency range of 50 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 100 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 200 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 300 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 400 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 1000 to 10,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 2000 to 8000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 4000 to 5000 Hz as measured by the ITTMT

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 10,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 8000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 4000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 4000 H as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 2000 Hz. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 to 1000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 1000 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 2000 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 4000 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 8000 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 10,000 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 100 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 1000 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 2000 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 5000 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 10,000 Hz to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 15,000 Hz to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 15,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 10,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 5000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 2000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 1000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 15,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 10,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 5000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 2000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 1000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 500 Hz as measured by the ITTMT. n some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 50 Hz to 100 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 1000 Hz to 15,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 2000 Hz to 10,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 100 Hz to 15,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 200 Hz to 10,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a phase angle of +45 degrees to −45 degrees over a frequency range of 500 Hz to 5,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a certain water entry pressure (“WEP”) as measured in accordance with the Capillary Piston Test (“CPT”). The CPT is described herein in the section titled “Test Procedures.” In some embodiments, the WEP described herein is a result of the effective stiffness (as described herein) of the at least one support layer or the assembly.

In some embodiments, the assembly is configured to provide a water entry pressure ranging from 1 psi to 450 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 2 psi to 200 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 5 psi to 100 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 50 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 20 psi to 25 psi when measured in accordance with the CPT.

In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 20 psi to 200 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 40 psi to 100 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 50 psi to 80 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 60 psi to 70 psi when measured in accordance with the CPT.

In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 200 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 100 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 80 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 70 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 60 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 50 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 40 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 10 psi to 20 psi when measured in accordance with the CPT.

In some embodiments, the assembly is configured to provide a water entry pressure ranging from 20 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 40 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 50 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 60 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 70 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 80 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 100 psi to 350 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 1.4 psi to 432 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 2.5 psi to 336 psi when measured in accordance with the CPT. In some embodiments, the assembly is configured to provide a water entry pressure ranging from 0.95 psi to 142 psi when measured in accordance with the CPT.

In some embodiments, the assembly is configured to provide a water entry pressure ranging from 200 psi to 350 psi when measured in accordance with the CPT.

In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 50 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 50 dB over the frequency range of 100 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 50 dB over the frequency range of 200 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 50 dB over the frequency range of 500 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a transmission loss of from 6 dB to 24 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 11 dB to 13 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 6 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 11 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 13 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 3 dB to 24 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the assembly is configured to provide a transmission loss of from 6 dB to 48 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 11 dB to 48 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 13 dB to 48 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 13 dB to 48 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT. In some embodiments, the assembly is configured to provide a transmission loss of from 24 dB to 48 dB over the frequency range of 50 to 20,000 Hz as measured by the ITTMT.

In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency. As used herein, “substantially constant as a function of frequency” means that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 20,000 Hz. The variance of transmission loss as a function of frequency can be determined by plotting transmission loss as a function of frequency. Frequencies on an x-axis of a plot of transmission loss versus frequency can be scaled to octaves using logarithmic scaling. An example of a scaling procedure according to the present disclosure is described herein in the “Test Procedures” section.

In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 100 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 300 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 400 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 500 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 1000 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 2000 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 5000 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 1000 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 15,000 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”).

In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 15,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 10,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 5000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 1000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 500 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss of the assembly is substantially constant as a function of frequency, such that the transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 50 to 100 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”).

In some embodiments, the transmission loss does not vary by more than 1.25 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss does not vary by more than 1 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss does not vary by more than 0.75 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss does not vary by more than 0.5 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss does not vary by more than 0.25 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”).

In some embodiments, the transmission loss varies by 0.25 dB/octave to 1.5 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss varies by 0.25 dB/octave to 1.25 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss varies by 0.25 dB/octave to 1 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss varies by 0.25 dB/octave to 0.75 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”). In some embodiments, the transmission loss varies by 0.25 dB/octave to 0.5 dB/octave over the frequency range of 50 to 20,000 Hz when measured by the Impedance Tube Transfer Matrix Test (“ITTMT”).

FIG. 1 depicts an exemplary embodiment of the present disclosure. As shown, assembly 100 includes a porous polymer membrane 104 in contact with a support structure in the form of support layer 102. The support layer 102 includes a plurality of openings 106 and the porous polymer membrane 104 includes a plurality of pores (not shown).

FIG. 2 also depicts an exemplary embodiment of the present disclosure. As shown, assembly 200 includes a porous polymer membrane 204 in direct contact with support structures in the form of support layers 202. The support layers 202 include a plurality of openings 206 and the porous polymer membrane 204 includes a plurality of pores (not shown). As shown, the porous polymer membrane 204 is sandwiched between the support layers 202. The assembly 200 may contain portions (e.g., portions 208) where the polymer membrane 204 is in contact with the support layers 202. In some embodiments, the plurality of openings 206 are uniform. In some embodiments, the thickness (not shown) of the support layers 202 is uniform. In some embodiments, the plurality of openings 206 are non-uniform. In some embodiments, the thickness (not shown) of the support layers 202 is non-uniform.

In some embodiments, the assembly is included in an acoustic device. In some embodiments, the acoustic device includes a speaker, a receiver, or any combination thereof.

Test Procedures

The following test procedures were used to generate the data in the examples section for Examples 1-8. The test procedures described herein are not intended to be limiting. The assembly, membrane, support layer and support structure numbers described in this section refer to the assembly, membrane, support layer and support structure numbers of the Examples section, infra.

Thickness: Thicknesses of the polymer membranes #1-10 and support layers #1-14 were measured herein using a commercially available Keyence LS-7010M measurement system. Some membranes (membrane #5, #6, #9) were less than 1 μm in thickness and could not be directly measured using the Keyence LS-7010M. Instead, the membranes were layered to achieve a thickness greater than 1 μm, which was the lower detection limit of the measurement system. The total thickness of the layered membranes were then measured using the Keyence LS-7010M and the thickness of a single layer was determined by dividing the total thickness of the layered sample by the number of layers.

The thickness of membrane #11 and support structures #1-3 were measured herein using a commercially available Polytec TMS-1200 TopMap μ. Lab microscope.

The thickness of membrane #12 was measured using a Keyence LS-7600 laser system, commercially available from Keyence America.

Flow Resistance: Airflow was measured using an ATEQ D520 Airflow Tester. The stackup of the samples were described for each example. In all configurations, the active area was assumed to be 1.77e-6 m⁻². The pressure at which each assembly was tested and resultant airflow was described herein in the Examples section. The airflow was measured in units of L/hr. The measured airflow was converted to flow resistance (Pa*s/m) as per the equation below

${{Flow}\mspace{14mu}{Resistance}\mspace{14mu}\left( {{Pa}*s\text{/}m} \right)} = {4.39e^{4}\frac{x({psi})}{y\left( \frac{L}{hr} \right)}}$ where x (psi) represents the air pressure used during the ATEQ measurement, and y (L/hr) was the volume flow rate measured directly on the ATEQ tester.

Young's Modulus: Herein, the Young's Moduli of the polymer membranes were measured in accordance with ISO 527-1:2012.

Bubble Point: Herein, the bubble point of the polymer membranes was measured using the ASTM F316. 9599-1 method.

Mass per unit area: Herein, mass per unit area was measured in accordance with ASTM D3776/D3776M-09a.

Water Entry Pressure Testing (Capillary Piston Test (“CPT”)): Water Entry Pressure (“WEP”) was measured for Examples 1-5 using a capillary flow porometer, model number CFP-1500-AE, purchased commercially from Porous Materials Inc. The tested sample was clamped by two polycarbonate plates in the lower piston in the tester. The top plate has a central hole of 8 mm and an O-ring surrounding the hole for waterproofing. The bottom plate has a central hole of 1.5 mm. For certain sample assemblies (e.g., 12, 13, 15, 16, 17, 31, 32, 33, and 34), the samples were prepared as described in each example, and the sample were clamped by the top and bottom polycarbonate plates. For other sample assemblies, the material, or layers of different materials were cut into pieces large enough to cover the whole O-ring on the top polycarbonate plate and clamped by the top and bottom polycarbonate plates. Before the test, deionized water was added to fill the 8 mm well in the top plate. The compression pressure was set to be 300 psi in the test program. The ramp rate of the pressure was 0.16 psi per second. The tester automatically and instantaneously detects the pressure (WEP) when water enters into the sample.

Effective Stiffness Measurement: Effective stiffness, k_(eff) (Pa/nm), was measured for Examples 1-8 using the Vibrational Displacement Test (“VDT”). The VDT includes the following: Samples were acoustically excited at 4 different sound pressures and the vibrational displacement at the center of the sample was measured. The excitation sound pressure was taken as the difference in sound pressure between the two microphones. The resulting data (i.e. the difference between the sound pressures in front of and behind the acoustic membrane assembly vs. displacement) was plotted and a linear regression performed. Effective stiffness was taken as the slope of the line passing through the measured data points and represents the extent to which a supported or unsupported sample assembly resists vibrational deformation in response to an applied acoustic plane wave. The vibrational displacement was measured using an MSA-500 micro system analyzer obtained commercially from Polytec Inc. The acoustic excitation was a sine wave centered at 200 Hz and generated by a JBL model 2426H compression driver. The output from the compression driver was necked down from 25.4 mm to 1.5 mm using an aluminum cone in order to match the diameter of the sample. The sound pressure of the wave was measured directly below and directly above the surface of the sample being tested using two probe microphones (model 377B26 microphones connected to a model 482C Series Sensor Signal Conditioner, obtained commercially from PCB Piezotronics Inc.). Polytec PSV 9.3 software was used to acquire the vibrational displacement data.

Transmission loss and phase testing: Transmission loss and phase angle testing were performed for Examples 1-8 by the Impedance Tube Transfer Matrix Test (“ITTMT”), which is a modified version of ASTM-E2611-09—the standard test method for measuring normal incidence sound transmission loss and phase based on the 4 microphone transfer matrix method. All modifications to ASTM-E2611-09 are set forth herein. An exemplary test set-up is shown in FIG. 3. The transfer matrix of the assembly was measured and we use T12 element of the transfer matrix as the acoustic impedance value for all the assemblies described in the examples.

An impedance tube was used to make measurements across a frequency range of 500 Hz to 20,000 Hz. The inner diameter of the tube was 8 mm. The impedance tube was designed in accordance with ASTM E1050-12 and ASTM E2611-09. A JBL 2426H compression driver was mounted at one end of the tube and powered by a Bruel and Kjaer Type 2735 amplifier connected to a 31-band ART 351 graphic equalizer. The measurement system used 4 Bruel and Kjaer Type 4138 microphones connected to a 4 channel Bruel and Kjaer Type 3160-A-042 LAN-XI Frontend with a generator output. Data was acquired and processed using Bruel and Kjaer PULSE Lab shop with Type 7758 Acoustic Material Testing Software, version 21.

The sample assemblies that were tested had an inner diameter of 1.5 mm, which was smaller than the inner diameter of the impedance tube. A pair of conical adapters was therefore required in order to mount the sample assemblies. The convergent cone had an inlet diameter of 8 mm and an outlet diameter of 1.5 mm. The divergent cone had an inlet diameter of 1.5 mm and an outlet diameter of 8 mm.

When using conical adapters, additional processing of the data was required to account for the converging geometry of the cones. Theoretical equations were derived to calculate the transfer matrices of the conical adapters and can be found in the literature (Hua, X. and Herrin, D., “Practical Considerations when using the Two-Load Method to Determine the Transmission Loss of Mufflers and Silencers,” SAE Int. J. Passeng. Cars—Mech. Syst. 6(2):1094-1101, 2013 & Mechel, F. P. (2008). Formulas of Acoustics. New York, N.Y.: Springer).

Transmission Loss Testing Before and After Pressure Testing: Some sample assemblies (e.g., those described in Example 2) were subjected to the following Air Pressure Test procedure. The purpose of this test was to replicate the pressure exerted on a membrane assembly in a device that was submerged in a given depth of water for a given duration of time. A transmission loss spectrum was measured before the pressure test and then remeasured immediately after the pressure test. The change in transmission loss, ΔTL (dB), due to the pressure test was calculated by subtracting the initial pre-test transmission loss from the post-test transmission loss.

Air Pressure Test: Air pressure testing was performed on some sample assemblies (e.g. those described in Example 2) by placing a sample assembly onto a base plate. A top plate was then added and bolted down to hold the sample assemblies securely in place. The testing conditions (ramp rate, pressure, hold time) were all controlled using a calibrated, programmable pressure box that was built in-house. The pressure box was capable of generating pressures ranging from 1 psi to 145 psi in increments of 0.5 psi. The pressurized line of air was connected to the base plate such that the pressure test occurred at the bottom surface of the membrane. Unless otherwise noted, each sample assembly was oriented such that the membrane was positioned between the base plate of the test fixture and the support layer of the sample assembly. Pressure testing was performed by increasing the pressure from 0 psi to targeted pressure with a 2.5 psi/sec ramp rate. After the targeted pressure was reached, the pressure was held constant for 10-minutes. Once the test was complete, the sample assemblies were removed from the fixture and the transmission loss was remeasured.

Transmission Loss Testing with Compression: Some transmission loss (“TL”) measurements were performed as a function of compression force applied to the sample assembly (e.g. those described in Example 3).

Compression testing was performed using an Economical Load and Force (ELF) Measurement System (purchased commercially from Tekscan) with a FlexiForce A201 force sensor calibrated across a 0-111 Newton measurement range. A fixture was designed to apply controlled compression force to samples during transmission loss and phase testing. A schematic drawing of this fixture is shown in FIG. 4. The force sensors were attached to the front plate using 4983 double sided pressure sensitive adhesive (purchased commercially from Tesa Tape Inc.).

Once the sample assembly to be tested was mounted between the left and right plates of the compression fixture on the impedance tube, a front plate was attached via a set of 4-40 flat head screws. The compression force was increased or decreased by tightening or loosening these flat head screws, respectively. Once a target compression force was reached, a transmission loss measurement was performed. After the measurement the screws were loosened to return the compression force to 0 Newtons and the process was repeated at progressively higher compression levels.

Procedure for Calculating % Contact: For support layers 1-6, 13, 14 and support structures 1-3 (because of the irregularity of some exemplary support structures), the contact percentage can be determined, as follows, from a representative area smaller than the total active area. A topography scan of a portion of support was measured using an optical profilometer (Polytec TopMap μLab), from the membrane-contacting side. The scanned topography in the depth range of 20 μm from the top was projected to a plane parallel to the support. The projected area will be larger than or equal to the area of physical contact between the membrane and support. The ratio between the projected area and the area of field-of-view of the topography scan (which can be considered as an upper bound of contact percentage) was determined by loading the image into ImageJ, converting it to 8-bit and then using the Analyze Particles feature in the software.

For support layer 7-12, within the active area, the area of physical contact between the membrane and support will be smaller than or equal to the total active area minus the area of perforations. The upper bound of contact percentage can be calculated as

${\%\mspace{14mu}{contact}\mspace{14mu}{area}} = {{\frac{{{Total}\mspace{14mu}{Area}} - {{Area}\mspace{14mu}{of}\mspace{14mu}{Perforations}}}{{Total}\mspace{14mu}{Area}}*100} = {\frac{D^{2} - {nd}^{2}}{D^{2}}*100}}$ where n is the number of perforations, d is the diameter of each perforation and D is the diameter of the active area, which is 1.5 mm for all sample assemblies. The diameter of each perforation was measured using an optical microscope (model VHX-5000, purchased commercially from Keyence Corporation).

FIG. 5 depicts a micrograph showing the top-most 20 μm of support layer 1. The dark regions in the image correspond to the fibers of the woven mesh and represent the areas of the support layer that come into contact with the membrane. The white regions in the image correspond to open area.

FIG. 6 depicts an optical micrograph showing the top-most 20 μm of support layer 5. The dark areas correspond to the non-woven fibers. The dark regions in the image correspond to the fibers of the non-woven support and represent the areas of the support layer that come into contact with the membrane. The white regions in the image correspond to open area.

FIG. 35 depicts a micrograph showing the top-most 20 μm of support structure 2, in the form of a second membrane. The dark regions in the image correspond to the nodes and fibrils of the support structure in the form of the second membrane and represent the areas of the support structure in the form of the second membrane that come into contact with the first membrane. The white regions in the image correspond to open area.

Procedure for Calculating % Open Area:

The % Open area can be calculated as % open area=100−% contact area

EXAMPLES

Preparation of Sample Assemblies The following tables (Table 1A and Table 1B) outline properties of exemplary membranes that are used in the foregoing examples. These properties are merely exemplary and not intended to be limiting.

TABLE 1A Properties of polymer membranes: Air Flow Effective Young's Membrane Thickness Resistance Stiffness Modulus # (μm) (MKS Rayls) (Pa/nm) (MPa) 1 9.4 4825 0.0044 31.1 2 13.3 12626 0.0053 29.6 3 15 49428 0.0405 48.3 4 1.2 3304 0.0006 359 5 0.0606 226 0.0009 Not measured 6 0.1545 218 0.0007 Not measured 7 125.5 1836 0.0587 4 8 1.75 1864 0.0036 72.63 9 0.83 919 0.0022 100.52

TABLE 1B Properties of polymer membranes: Water Entry Mass Max Pressure per Bubble Pore Membrane WEP Area Point Size # (psi) (g/m²) (psi) (μm) 1 20.2 1.83 16.6 0.73 2 43.8 3.74 30.1 0.40 3 110.8 7.4 56 0.22 4 12.4 0.24 31.9 0.38 5 Not measured 0.009 Not measured Not measured 6 2.5 0.029 Not measured Not measured 7 10.8 5.34 1.514 7.96 8 11.6 0.1679 13.56 0.89 9 5.8 0.0953 4.85 2.49

Polymer membranes #s 1-9 above were prepared according to the following methods.

TABLE 2 Membrane Preparation Methods Membrane # Preparation Method 1 Prepared according to the general teachings of U.S. Pat. No. 3,953,566. 2 Prepared according to the general teachings of U.S. Pat. No. 3,953,566 3 Prepared according to the general teachings of U.S. Pat. Nos. 3,953,566 and 6,541,589 4 Prepared according to the general teachings of U.S. Pat. Nos. 3,953,566 and 9,775,933 5 Prepared according to the general teachings of U.S. Pat. No. 3,953,566 Membrane thickness was measured as follows. 128 individual layers were stacked together and a thickness of 7.76 μm was measured as described herein. The thickness of a single layer was determined by dividing the total thickness by the number of layers. The thickness of this membrane was determined to be 60.6 nm 6 Prepared according to the general teachings of U.S. Pat. No. 3,953,566. Membrane thickness was measured as follows. 32 individual layers were stacked together and a thickness of 4.95 μm was measured as described herein. The thickness of a single layer was determined by dividing the total thickness by the number of layers. The thickness of this membrane was determined to be 154.5 nm 7 Prepared according to the general teachings of U.S. Pat. Nos. 3,953,566 and 5,814,405. 8 Prepared according to the general teachings of U.S. Pat. No. 3,953,566 9 Prepared according to the general teachings of U.S. Pat. No. 3,953,566. Membrane thickness was measured as follows. 2 individual layers were carefully stacked together and a thickness of 1.66 μm was measured as described herein. The thickness of a single layer was determined by dividing the total thickness by the number of layers. The thickness of this membrane was determined to be 0.83 μm

The following tables outline properties of exemplary support layers that are used in the foregoing examples. These properties are merely exemplary and not intended to be limiting.

TABLE 3A Properties of support structures in the form of the following exemplary support layers: Support Support Air-Flow Effective % Layer Layer Material Resistance Open # Type Composition (MKS Rayl) Area 1 Woven PET 54 74.24 2 Woven PET 79 52.32 3 Woven PET 171 37.27 4 Bi-Component Co-PET Sheath w PET 43 87.97 Mesh Core 5 Non Woven Co-Polyester 67 83.16 6 Apertured Film Polyethylene 157 77.68 7 Perforated Plate Brass (Perforations: 19 × 704 9 100 μm) 8 Perforated Plate Brass (Perforations: 56 × 186 24 100 μm) 9 Perforated Plate Fiberglass 753 9 (Perforations: 19 × 100 μm) 10 Perforated Plate Fiberglass 613 26 (Perforations: 19 × 175 μm) 11 Perforated Plate PET (Perforations: 85 × 1129 30.6 90 μm) 12 Perforated Plate PET (Perforations: 85 × 352 45.7 110 μm) 13 Woven Nylon-6-6 1458 36.13 14 Perforated Plate Stainless Steel 1212 15.17

TABLE 3B Properties of support structures in the form of the following exemplary support layers: Support Largest Dimension Effective Layer of Single Opening Thickness Stiffness # % Contact (μm) (μm) (Pa/nm) 1 25.76 105 64 1.053 2 47.68 33 40 0.243 3 62.73 20 70 0.792 4 12.03 330 80 1.163 5 16.84 350 127 0.844 6 22.32 220 109 0.066 7 91 96 410 22.64 8 76 96 410 21.90 9 91 100 381 4.38 10 74 175 381 1.42 11 69.4 90 127 4.24 12 54.3 110 130 2.9 13 63.87 10 64 0.255 14 84.83 85 89 6.94

Certain non-limiting sample assemblies and comparative sample assemblies described and tested herein were prepared as follows.

All example sample assemblies (with the exception of sample assembly 12 and 13) and comparative sample assemblies are comprised of at least one adhesive-backed fiberglass sample carrier, referred to simply as fiberglass sample carriers from this point forward. The fiberglass sample carriers were prepared by applying a double-sided pressure sensitive adhesive to one side of a fiberglass sheet (purchased commercially from McMaster-Carr, product #1331T37). The fiberglass/adhesive sheets were then laser cut into coupons. A 1.5 mm diameter hole was then fabricated in the center that aligned with the inner bore of the impedance tube and corresponds to the active area of the sample to be measured.

Comparative Sample Assemblies:

Certain non-limiting comparative sample assemblies were prepared as follows: A piece of membrane was positioned on a smooth and level surface so that the membrane was flat and free of any wrinkles. The adhesive release liner was removed from a pre-cut fiberglass sample carrier to expose the adhesive. With adhesive layer exposed, the sample carrier was gently placed onto the membrane and any excess membrane was cut away from the perimeter of the sample carrier. The sample carrier was then placed onto an alignment jig with membrane side facing up. The release liner was removed from a second fiberglass sample carrier and placed onto the alignment jig with adhesive side facing down, towards the membrane. Low pressure (manually applied and not measured) was applied to bring the bottom and top sample carriers together to form an assembly having the following stack up: fiberglass sample carrier/membrane/fiberglass sample carrier. The stack up for comparative sample assemblies are shown in Table 4.

Sample Assemblies

Certain non-limiting sample assemblies with perforated adhesive-backed fiberglass support layers (e.g., Assemblies 15-17, 33, 34) were prepared according the following procedure. Perforated adhesive-backed fiberglass support layers were fabricated in a similar manner as adhesive-backed fiberglass sample carriers (described above), with the exception that multiple small diameter perforations (openings) were made instead of a single large 1.5 mm diameter hole. The number of perforations and their diameters are shown in Tables 3A and 3B. Sample assemblies were then prepared as described herein with the exception that one of the fiberglass sample carriers was substituted with a pre-cut adhesive-backed perforated fiberglass support, referred to simply as a perforated fiberglass support layer from this point forward. The stack up for these assemblies are shown in Tables 3A and 3B.

Certain non-limiting sample assemblies with woven and/or non-woven support layers (e.g., assemblies 1-11, 14, 18-30) were prepared as follows. Woven and non-woven support materials were cut from the roll into small (6 mm×6 mm) square pieces and set aside. The adhesive release liner was removed from a pre-cut fiberglass sample carrier and adhered to a pre-cut square of the support material such that the support covered the 1.5 mm diameter hole at the center of the fiberglass sample carrier. With a majority of the adhesive still exposed, the polymer membrane was then attached to the sample carrier. The fiberglass sample carrier with the support layer and membrane attached was then placed membrane side up on an alignment jig. The adhesive release liner from a second fiberglass sample carrier was removed and placed adhesive side down onto the alignment jig. Light pressure was applied to bring the bottom and top sample carriers together to form an assembly having the following stack up: fiberglass carrier/adhesive/support/membrane/adhesive/fiberglass carrier. In some sample assemblies (e.g., assemblies 1-8, 10, 11, 14, 18, 20, 22, 23, 25-28)) a second fiberglass sample carrier with support layer was used to form an assembly having the following stack up: fiberglass carrier/adhesive/support/membrane/support/adhesive/fiberglass carrier. Sample assembly 29 was pressurized at 17 psi for 10 minutes using the same procedure described in the Test Procedures section to improve the attachment between the polymer membrane and the support layer. Refer to Tables 3A and 3B for additional stack up information for assemblies with at least one woven or non-woven support.

Certain non-limiting assemblies with perforated PET support layer(s) (e.g., Assemblies 31, 32) were prepared as follows: First, double sided pressure sensitive adhesive was applied to one side of a PET sheet with thickness of 127-130 μm. The PET/adhesive sheets were then laser cut into coupons. Perforations (openings) were formed in the 1.5 mm diameter circular area at the center of the coupon. The number of perforations and their diameters are shown in Tables 3A and 3B. With the adhesive layer exposed, the coupon with perforations can be attached to a polymer membrane and act as a support layer. A fiberglass sample carrier was then attached to the opposite side of the membrane to form an assembly having the following stack up: fiberglass sample carrier/adhesive/membrane/adhesive/PET support.

Certain assemblies with brass support layers (e.g., Assemblies 12, 13) were prepared as follows. Brass coupons were prepared from sheet material. Perforations (openings) were formed in the 1.5 mm diameter circular area at the center of the coupons. The number of perforations and their diameters are shown in Tables 3A and 3B. The membrane was clamped between two brass support plates to form an adhesive-free assembly with the following stack up: brass support/membrane/brass support. In this procedure, the perforations on both coupons align with accuracy.

Exemplary Lamination procedure:

In some embodiments, the polymer membrane is laminated to the at least one support layer. While lamination can be performed using any method, in some embodiments, the polymer membrane is laminated to the at least one support layer using a mini hot roll laminator (model HL-200, purchased commercially from Chem Instruments Inc.). To improve handleability, the support and membrane can be cut into 3-inch×6-inch strips and placed between two pieces of 25.4-μm-thick kapton (purchased commercially from DuPont) cut into strips slightly larger than the membrane and support layer. The sample assemblies can then be inserted between two rollers (a hot roll and a nip roll) and laminated. The stack up can be as follows: kapton/ePTFE/support layer/kapton. When woven meshes (e.g., product #34-33 and 6-105, Sefar Inc. Holding AG) are used as a support layer, lamination can be performed at a temperature of 265 C, a pressure of 40 psi between the hot roll and the nip roll and a line speed of 45 cm/min. When bi-component mesh (e.g., product #28T1, Unitika Ltd.) is used as a support layer, lamination was performed at a temperature of 185° C., a pressure of 40 psi between the hot roll and nip roll and a line speed of 45 cm/min. When a non-woven material was used (product #133, HDK Industries) as the support layer, lamination was performed at a temperature of 180 C, a pressure of 25 psi between the hot roll and the nip roll and a line speed of 400 cm/min.

The orientation can be such that the polymer membrane is closest to the hot roll and the support is closest to the nip roll. In some embodiments, a mesh support layer (product #28T1, Unitika) can be laminated onto the top and bottom surface of the membrane. The stack up for these sample assemblies can be as follows: kapton/mesh support layer/ePTFE/mesh support layer/kapton. The sample assemblies were inserted between the rollers a first time to laminate the mesh support layer to the top surface of the membrane. The sample assemblies can then be flipped over and inserted a second time to laminate the mesh support layer to the bottom surface of the membrane. After lamination, the top and bottom kapton layers can be removed.

TABLE 4 Exemplary configurations of Sample Assemblies: The following table lists the configuration of the assemblies used in the foregoing Examples. The “membrane #” and “support layer #” designated herein refer to Tables 1A, 1B, and 2 respectively. Support No. of Assembly layer Membrane support Attachment # # # layers method Stackup 1 1 1 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 2 1 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 3 1 3 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 4 1 4 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 5 1 5 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 6 1 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 7 1 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 8 1 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 9 1 2 1 Layered Fiberglass sample carrier/polymer membrane/support/fiberglass sample carrier 10 1 2 2 Layered Fiberglass sample cam er/support/polymer membrane/support/fiberglass sample carrier 11 1 3 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 12 8 2 2 Layered Support/polymer membrane/support 13 7 2 2 Layered Support/polymer membrane/support 14 1 3 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 15 9 2 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support 16 9 2 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support 17 9 3 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support 18 3 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 19 2 3 1 Laminated Fiberglass sample carrier/polymer membrane/support/fiberglass sample carrier 20 3 1 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 21 4 3 1 Laminated Fiberglass sample carrier/polymer membrane/support/fiberglass sample carrier 22 4 3 2 Laminated Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 23 5 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 24 5 7 1 Laminated Fiberglass sample carrier/polymer membrane/support/fiberglass sample carrier 25 1 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 26 6 2 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 27 13 8 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 28 13 9 2 Layered Fiberglass sample carrier/support/polymer membrane/support/fiberglass sample carrier 29 14 8 1 Layered Fiberglass sample carrier/polymer membrane/support/fiberglass sample carrier 30 4 4 1 Laminated Fiberglass sample carrier/polymer membrane/support/fiberglass sample carrier 31 11 4 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support 32 12 4 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support 33 10 4 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support 34 9 6 1 Adhesive Fiberglass sample carrier/polymer membrane/adhesive/support

TABLE 5 Comparative Sample Assemblies: The following table lists the configuration of the comparative sample assemblies used in the foregoing Examples. Comparative Sample Support No. of Assembly layer Membrane support Attachment # # # layers method Stackup  1c None 1 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  2c None 2 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  3c None 3 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  4c None 4 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  5c None 5 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  6c None 2 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  7c None 2 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  8c None 2 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier  9c None 2 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 10c None 3 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 11c None 3 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 12c None 3 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 13c None 2 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 14c None 8 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 15c None 9 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 16c None 4 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 17c None 6 0 Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier Properties of Sample Assemblies and Comparative Sample Assemblies

The following table lists exemplary properties of certain sample and comparative sample assemblies. All properties are measured as described herein.

TABLE 6 Properties of certain Sample Assemblies: Water Pressure Entry difference Sample Pressure Airflow for airflow Effective Assembly WEP Resistance resistance Stiffness # (psi) (Rayls) test (psi) (Pa/nm) 1 59.940 4843 0.17 1.42 2, 6, 7, 8, 10, 25 120.318 15555 0.17 2.29 3, 11, 14 199.4 62275 0.50 4.25 4 71.76 3227 0.17 25.5 5 Not measured 204 0.17 1.623 9 124.088 13845 0.17 2.2872 12 173.485 84014 0.7 29.8 13 209.813 357416 0.7 29.8 15, 16 224.790 67642 0.17 3.81 17 336.360 434405 1 2.9 18 92.290 15760 0.17 0.739 19 156.745 125508 0.5 0.4524 20 57.123 5732 0.17 1.46 21 202.462 31058 0.5 0.6971 22 172.499 49200 0.5 2.04 23 107.594 12050 0.17 1.52 24 10.908 2522 0.17 2.41 25 120.318 15555 0.17 2.2872 26 149.459 14822 0.17 1.19 27 36.12 4705 0.17 0.657 28 12.732 3984 0.17 .657 29 80.114 2939 0.17 2.47 30 15.015 3792 0.17 .198 31 225.789 24012 0.17 2.32 32 211.157 12437 0.17 1.66 33 162.933 31198 0.17 2.75 34 12.1 948 0.17 1.87

TABLE 7 Properties of certain Comparative Assemblies: Pressure difference Comparative Water Entry used for Sample pressure Airflow airflow Effective Assembly (“WEP”) Resistance resistance Stiffness # (psi) (Rayls) test (psi) (Pa/nm)  1c 20.185 4825 0.17 0.0044 2c, 6c, 7c, 43.526 12626 0.17 0.0053 8c, 9c, 13c 3c, 10c, 11c, 12c 110.787 49428 0.5 0.0405 4c, 16c 12.413 3304 0.17 0.0006  5c Not measured 226 0.17 .0009 14c 11.576 1864 0.17 0.0036 15c 5.788 919 0.17 0.0022 17c 2.5 218 0.17 0.0007

Example 1—Non-Limiting Embodiments Exhibiting Constant Acoustic Transmission and Resistive Behavior

For all the sample assemblies including the comparative sample assemblies, transmission loss and phase angle testing was performed as described in Test Procedures section.

The transmission loss data of the sample assemblies and comparative sample assemblies are shown in Table 8 at six discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, 20,000 Hz). The transmission loss vs. frequency spectra are shown in FIGS. 7 to 18.

TABLE 8 Transmission loss of sample assemblies and comparative sample assemblies Transmission Loss (dB) Example Assembly 500 1,000 2,000 5,000 10,000 20,000 # # Hz Hz Hz Hz Hz Hz 1a  1 16.94 17.36 17.61 17.47 17.78 17.89  1c 13.75 8.50 4.72 1.34 0.38 1.20 1b  2 23.13 24.16 24.27 24.28 24.57 23.92  2c 18.91 15.17 10.35 3.83 1.09 2.27 1c  3 31.81 31.33 31.80 31.83 32.03 27.75  3c 29.65 24.44 18.83 10.45 3.51 2.10 1d  4 11.39 11.55 11.59 11.51 11.78 11.77  4c 12.02 8.79 4.93 1.42 0.53 0.34 1e  5 3.48 2.96 2.99 2.95 3.00 3.10  5c 1.81 1.79 1.74 0.77 0.20 0.25 1f  9 29.16 29.36 29.21 28.60 27.67 23.93  9c 13.35 9.60 5.52 1.72 0.50 2.37 10 25.15 24.71 25.00 25.23 25.87 25.80 1g 12 41.31 41.38 41.25 40.98 41.27 40.44 1g 13 49.18 50.27 49.90 49.27 50.02 48.81 1h 18 25.81 25.80 26.00 26.10 26.80 27.30 2c 18.91 15.17 10.35 3.83 1.09 2.27 1g 19 47.20 47.80 47.20 45.90 42.40 36.90 1g 20 18.10 18.30 18.50 18.40 18.70 18.70 1g 21 37.70 37.80 38.20 37.60 37.00 34.30 1g 23 23.30 23.00 23.70 23.60 23.50 22.30 1g 24 15.20 15.30 15.50 15.50 15.60 14.20 1i 25 25.90 26.80 26.90 26.70 26.90 27.20  13c 21.40 16.80 13.60 6.50 2.30 7.80 1g 26 25.19 25.76 25.69 25.05 23.83 18.13 1j 27 15.92 16.42 16.32 15.91 15.53 12.62  14c 10.14 7.43 4.14 1.16 0.55 0.38 1k 28 14.27 14.39 14.23 13.92 13.75 12.27  15c 6.16 5.27 3.33 0.91 0.25 0.47 1g 29 15.44 15.78 15.81 15.52 15.52 15.31 1g 30 17.80 18.16 18.04 17.46 16.36 13.80 1l 34 6.32 6.49 6.48 6.37 6.43 6.36  17c 1.78 1.63 1.03 0.26 0.10 0.52

The phase angle data of the sample assemblies are shown in Table 10 at six discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, 20,000 Hz). The raw phase angle vs. frequency spectra of the tested sample assemblies are shown in FIGS. 7 to 18.

TABLE 9 Phase angle of sample assemblies & comparative sample assemblies: Phase Angle (degrees) Example Assembly 500 1,000 2,000 5,000 10,000 20,000 # # Hz Hz Hz Hz Hz Hz 1a  1 2.91 3.03 2.24 0.96 −0.78 −2.74  1c −61.20 −64.00 −74.10 −76.00 −69.50 25.90 1b  2 6.50 3.69 1.56 −2.71 −10.20 −23.50  2c −58.20 −68.40 −71.60 −75.10 −31.60 79.70 1c  3 3.82 0.74 −0.72 −7.73 −21.20 −42.90  3c −64.90 −74.30 −79.80 −84.10 −86.10 82.90 1d  4 2.35 2.50 0.89 −1.23 −4.32 −12.60  4c −43.60 −60.80 −75.20 −80.20 −86.07 −31.10 1e  5 −4.18 −1.72 0.73 −1.43 −2.86 −3.35  5c 1.79 −10.40 −24.50 −60.60 −76.70 −28.50 1f  9 −0.36 −2.17 −6.46 −16.92 −32.47 −51.92  9c −69.1 −68.8 −71.72 −68.65 56.05 75.94 10 9.39 7.79 4.65 1.22 −3.92 −15.72 1g 12 1.82 0.75 1.60 1.38 0.40 1.40 1g 13 3.33 2.18 −0.20 0.87 1.59 3.52 1h 18 2.78 2.96 2.82 2.09 −1.48 −10.48  2c −58.20 −68.40 −71.60 −75.10 −31.60 79.70 1g 19 −3.35 −5.98 −5.79 −23.22 −49.84 −65.23 1g 20 0.71 2.56 1.58 0.07 −2.62 −6.27 1g 21 −2.07 −0.74 −3.30 −10.81 −22.17 −37.77 1g 23 8.12 4.98 2.24 −6.42 −15.44 −38.18 1g 24 0.25 2.47 2.49 2.20 2.07 3.53 1i 25 1.16 1.99 1.13 −2.62 −7.19 −14.31  13c −44.64 −64.00 −75.08 −83.62 −86.59 81.72 1g 26 −3.14 −1.8 −6.67 −18.64 −36.32 −58.63 1j 27 3.20 1.56 −1.22 −4.24 −10.59 −23.77  14c −36.35 −52.86 −69.86 −79 −81.74 4.4508 1k 28 1.06 1.74 −0.15 −1.42 −5.00 −14.30  15c −17.50 −32.67 −55.12 −72.93 −83.36 52.56 1g 29 2.94 2.60 1.31 1.81 −1.27 3.87 1g 30 1.93 −0.35 −5.02 −14.89 −30.26 −42.71 1l 34 2.88 3.39 2.29 2.26 3.77 5.44  17c −14.70 −33.50 −52.50 −85.10 −84.80 −36.03

As shown, the sample assemblies exhibit phase angles falling within the range of +45 degrees to −45 at the tested frequencies, while the comparative sample assemblies exhibit phase angles falling outside of the ranges of +45 degrees to −45 at some of the tested frequencies.

The slope of the transmission loss (in dB/Octave) for each sample assembly and for each comparative sample assembly was measured through a linear regression over the discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, 20,000 Hz).

The frequencies were scaled to octaves using the following procedure:

The number of octaves between 500 Hz and 500 Hz is

${\log_{2}\left( \frac{500}{500} \right)} = 0$

The number of octaves between 500 Hz and 1000 Hz is

${\log_{2}\left( \frac{1000}{500} \right)} = 1$

The number of octaves between 500 Hz and 2000 Hz is

${\log_{2}\left( \frac{2000}{500} \right)} = 2$

The number of octaves between 500 Hz and 5000 Hz is

${\log_{2}\left( \frac{5000}{500} \right)} = 3.32$

The number of octaves between 500 Hz and 10,000 Hz is

${\log_{2}\left( \frac{10000}{500} \right)} = 4.32$

The number of octaves between 500 Hz and 20,000 Hz is

${\log_{2}\left( \frac{20000}{500} \right)} = 5.32$

The slope of the transmission loss spectrum can then be determined by performing a linear regression on the transmission loss data over the above-calculated octaves.

For comparative sample assemblies, the transmission loss value will decrease with frequency in low frequency range and then increase with frequency in high frequency range. The linear regression is performed in the low frequency range for comparative sample assemblies. As shown below in Tables 10-11, for a given membrane, the slope of the transmission loss of sample assemblies was closer to zero than the slope the transmission loss of the comparative sample assemblies, indicating that the sample assemblies provided a more predominantly constant sound transmission profile. Specifically, as illustrated by the non-limiting examples below, in some embodiments of the present disclosure, the absolute value of the slope of transmission loss is 1.5 dB/octave or less (i.e., the transmission loss ranges from is −1.5 dB/octave to 1.5 dB/octave) over a 500 Hz to 20,000 Hz range. Put differently, in the non-limiting examples of Table 10, transmission loss does not vary by more than 1.5 dB/octave over the frequency range of 500 to 20.000 Hz

TABLE 10 Slope of the transmission loss of sample assemblies and comparative sample assemblies: Example Assembly Slope of TL (dB/Octave) over # # 500 Hz-20,000 Hz range 1a  1 0.152  1c −3.072 1b  2 .136  2c −4.293 1c  3 −.469  3c −5.528 1d  4 −0.127  4c −2.293 1e  5 −0.0473  5c −0.3932 1f  9 −0.833  9c −3.054 10 0.185 1g 12 −0.130 1g 13 −0.088 1h 18 0.277  2c −4.293 1g 19 −1.812 1g 20 0.107 1g 21 −0.524 1g 23 −0.092 1g 24 −0.105 1i 25 0.170  13c −4.435 1g 26 −1.091 1j 27 −.512  14c −1.916 1k 28 −0.321  15c −1.481 1g 29 −0.047 1g 30 −0.682 1l 34 −0.003  17c −0.435

Example 2—Non-Limiting Embodiments Exhibiting Improved Pressure Challenge Resistance

For all the sample assemblies including the comparative sample assemblies, transmission loss and phase angle testing was performed as described in Test Procedures section. Sample assemblies were subjected to a pressure test described in Table 11 below with a ten-minute hold time.

TABLE 11 Test Pressures of sample assemblies and comparative sample assemblies Challenge Example Assembly Pressure # # (psi) 2a  6 2.2  6c 2.2 2b  7 14.5  7c 14.5 2c  8 43.5  8c 43.5 2d 11 43.5  10c 43.5 2e 15 14.5  7c 14.5 2f 16 43.5  8c 43.5 2g 17 43.5  10c 43.5 2h 22 116  12c 116 2i 27 17 29 17 2j 28 10 2k 31 10 32 10 33 10  16c 10

The pre vs. post test transmission loss and phase data was measured as described in the Test Procedures Section. For the sample assemblies and the comparative sample assemblies, the transmission loss before and after the pressure test, as well as the relative change in transmission loss, are shown in below in Tables 12 to 14 at six discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, and 20,000 Hz). The raw transmission loss and phase angle vs. frequency spectra are shown in FIGS. 19 to 29. As shown, for a given membrane, the change of transmission loss before and after the pressure test is smaller than that for comparative sample assemblies, indicating that the sample assemblies provided a more robust acoustic performance and improved burst strength against pressure challenge.

TABLE 12 Transmission loss of sample assemblies and comparative sample assemblies before pressure challenge Challenge Transmission Loss Before Pressure Challenge (dB) Example Assembly Pressure 500 1,000 2,000 5,000 10,000 20,000 # # (psi) Hz Hz Hz Hz Hz Hz 2a  6 2.2 24.67 25.16 25.31 25.32 25.91 26.00  6c 2.2 20.40 15.91 10.58 3.75 0.59 1.50 2b  7 14.5 24.73 25.23 25.49 25.39 26.10 25.79  7c 14.5 23.23 18.32 13.81 6.25 1.89 2.36 2c  8 43.5 24.30 24.66 24.67 24.72 25.21 24.98  8c 43.5 21.64 17.47 12.06 4.69 0.83 1.19 2d 11 43.5 32.44 31.92 31.72 31.53 30.69 26.10  10c 43.5 18.78 14.29 9.09 2.38 0.31 5.55 2e 15 14.5 37.83 38.29 38.17 37.50 37.67 37.88  7c 14.5 23.23 18.32 13.81 6.25 1.89 2.36 2f 16 43.5 36.88 37.30 37.08 36.69 36.90 37.05  8c 43.5 21.64 17.47 12.06 4.69 0.83 1.19 2g 17 43.5 47.42 47.07 46.94 46.93 46.95 47.09  10c 43.5 18.78 14.29 9.09 2.38 0.31 5.55 2h 22 116 33.30 33.50 33.50 32.90 32.70 29.90  12c 116 29.65 24.44 18.83 10.45 3.51 2.10 2i 27 17 15.92 16.42 16.32 15.91 15.53 12.62 29 17 15.44 15.78 15.81 15.52 15.52 15.31 2j 28 10 14.27 14.39 14.23 13.92 13.75 12.27 2k 31 10 30.42 30.10 29.60 29.20 29.30 28.40 32 10 24.60 24.70 24.40 24.20 24.10 23.40 33 10 27.10 27.40 26.20 25.00 24.20 23.10  16c 10 12.37 9.16 5.12 1.47 0.54 0.33

TABLE 13 Transmission loss of sample assemblies and comparative sample assemblies after pressure challenge Challenge Transmission Loss After Pressure Challenge (dB) Example Assembly Pressure 500 1,000 2,000 5,000 10,000 20,000 # # (psi) Hz Hz Hz Hz Hz Hz 2a  6 2.2 23.59 24.96 25.52 25.61 26.63 26.36  6c 2.2 13.48  9.00  5.33  1.64 1.12 4.56 2b  7 14.5 24.15 24.71 25.00 25.23 25.86 25.80  7c 14.5 13.35  9.60  5.52  1.72 0.50 2.31 2c  8 43.5 24.40 23.94 24.30 24.40 25.10 25.14  8c 43.5 Burst Burst Burst Burst Burst Burst 2d 11 43.5 33.21 33.35 32.67 31.66 29.48 24.15  10c 43.5 28.60 23.66 18.01 10.39 4.13 1.22 2e 15 14.5 38.77 39.80 38.84 38.67 38.63 38.20  7c 14.5 13.35  9.60  5.52  1.72 0.50 2.31 2f 16 43.5 38.49 38.43 37.85 37.88 37.86 37.64  8c 43.5 Burst Burst Burst Burst Burst Burst 2g 17 43.5 49.50 49.51 49.75 50.14 49.66 49.19  10c 43.5 28.60 23.66 18.01 10.39 4.13 1.22 2h 22 116 31.70 31.80 32.30 33.70 35.10 34.70  12c 116 Burst Burst Burst Burst Burst Burst 2i 27 17 16.60 17.05 16.94 16.75 16.56 14.49 29 17  2.75  2.56  0.82 −0.83 −2.82 −0.06 2j 28 10 14.28 14.65 14.54 14.35 14.24 13.27 2k 31 10 30.00 29.20 28.80 28.50 28.20 27.50 32 10 25.30 25.70 25.50 25.10 24.50 23.10 33 10 25.50 24.50 23.00 21.90 21.10 20.10  16c 10  3.04  1.11  1.32  0.64 0.34 0.51

TABLE 14 Change in transmission loss of sample assemblies and comparative sample assemblies Challenge Change in Transmission Loss, ΔTL (dB) Example Assembly Pressure 500 1,000 2,000 5,000 10,000 20,000 # # (psi) Hz Hz Hz Hz Hz Hz 2a  6 2.2 −1.08  −0.20 0.21 0.29 0.72 0.36  6c 2.2 −6.92  −6.91 −5.25  −2.11  0.53 3.06 2b  7 14.5 −0.58  −0.52 −0.49  −0.16  −0.24  0.01  7c 14.5 −9.88  −8.72 −8.29  −4.53  −1.40  −0.05  2c  8 43.5 0.10 −0.72 −0.37  −0.32  −0.11  0.16  8c 43.5 Burst Burst Burst Burst Burst Burst 2d 11 43.5 0.77  1.43 0.95 0.13 −1.21  −1.95   10c 43.5 9.82  9.37 8.92 8.01 3.82 −4.33  2e 15 14.5 0.94  1.51 0.67 1.16 0.96 0.32  7c 14.5 −9.88  −8.72 −8.29  −4.53  −1.40  −0.05  2f 16 43.5 1.61  1.13 0.77 1.19 0.96 0.59  8c 43.5 Burst Burst Burst Burst Burst Burst 2g 17 43.5 2.08  2.45 2.81 3.21 2.71 2.11  10c 43.5 9.82  9.37 8.92 8.01 3.82 −4.33  2h 22 116 −1.60  −1.70 −1.20  0.80 2.40 4.80  12c 116 Burst Burst Burst Burst Burst Burst 2i 27 17 0.68  0.63 0.62 0.84 1.03 1.87 29 17 0.21  0.17 0.09 0.07 −0.08  −0.31  2j 28 10 0.01  0.26 0.31 0.43 0.49 1.00 31 10 −0.42  −0.90 −0.80  −0.70  −1.10  −0.90  2k 32 10 0.70  1.00 1.10 0.90 0.40 −0.30  33 10 −1.60  −2.90 −3.20  −3.10  −3.10  −3.00   16c 10 −9.33  −8.05 −3.80  −0.83  −0.20  0.18

Example 3—Non-Limiting Embodiments Exhibiting Improved Compression Resistance

Transmission loss and phase angle testing on assemblies under compression was performed as described in section Test Procedures section. Three different forces (5 N, 10 N, 20 N) were applied to the sample assembly 14 and comparative assembly 11c and the transmission loss and phase angle are measured with the assemblies under compression. The transmission loss without compression force is also measured.

The raw transmission loss and phase angle vs. frequency spectra as a function of compression force is shown in FIG. 30. The transmission loss and phase data are shown in Tables 15 and 16 at six discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, and 20,000 Hz).

TABLE 15 Compressive forces applied to sample assemblies and comparative sample assemblies during transmission loss measurements Compressive Example Assembly Force # # (N) 3a 14 0, 5, 10, 20  11c 0, 5, 10, 20

TABLE 16 Transmission loss of sample assemblies and comparative sample assemblies as a function of compressive force applied to each assembly during the measurement. Compression Transmission Loss (dB) Example Assembly Force 500 1,000 2,000 5,000 10,000 20,000 # # (N) Hz Hz Hz Hz Hz Hz 3a 14 0 39.49 37.07 37.62 37.12 36.47 33.77 5 36.37 38.26 38.04 37.82 36.78 33.44 10 37.02 39.02 38.62 38.06 37.16 33.32 20 39.16 40.57 39.32 38.62 37.63 32.94  11c 0 26.14 23.17 17.51 9.06 1.98 4.39 5 30.67 26.77 21.30 13.24 5.19 3.27 10 39.10 32.39 26.40 18.39 11.59 3.02 20 43.70 37.44 31.65 24.10 16.44 5.91

TABLE 17 Change in transmission loss of sample assemblies and comparative sample assemblies due to compression testing. Note that the change in TL is relative to 0 N (no compression). Compression Change in transmission Loss (dB) Example Assembly Force 500 1,000 2,000 5,000 10,000 20,000 # # (N) Hz Hz Hz Hz Hz Hz 3a 14 5 −3.12 1.19 0.42 0.70 0.31 −0.33 10 −2.47 1.95 1.00 0.94 0.69 −0.45 20 −0.33 3.50 1.70 1.50 1.16 −0.83  11c 5 4.53 3.60 3.79 4.18 3.21 −1.12 10 12.96 9.22 8.89 9.33 9.61 −1.37 20 17.56 14.27 14.14 15.04 14.46 1.52

TABLE 18 Phase angle of sample assemblies and comparative sample assemblies as a function of compressive force applied to each assembly during the measurement. Compression Phase (degrees) Example Assembly Force 500 1,000 2,000 5,000 10,000 20,000 # # (N) Hz Hz Hz Hz Hz Hz 3a 14 0 −4.74 −1.71 −3.24 −14.67 −29.72 −45.72 5 −0.30 −2.52 −4.89 −17.18 −36.49 −52.36 10 −7.69 −2.43 −7.00 −16.44 −38.34 −54.07 20 −9.60 −2.21 −8.55 −20.11 −44.67 −59.85  11c 0 −76.73 −63.09 −75.11 −83.26 −83.96 60.76 5 −59.60 −71.20 −78.08 −87.61 −89.63 57.15 10 −74.36 −86.90 −85.03 −89.88 −94.03 −35.94 20 −67.21 −74.90 −76.38 −87.01 −86.18 −52.70

Example 4—Non-Limiting Embodiments Exhibiting Improved Acoustic Consistency

For sample assembly 25 and comparative sample assembly 13c, 5 samples are made and tested for transmission loss and phase angle. The variability between parts is evaluated by the standard deviation of transmission loss between samples at each of frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, and 20,000 Hz). The mean transmission loss and phase angle among the 5 samples are tabulated in Table 19 and Table 20. The standard deviation of transmission loss is tabulated in Table 21 and shown in FIG. 32. The raw transmission loss and phase angle is shown in FIG. 31, and the error bars in these figures are the distribution of the measured values. As shown the sample assemblies exhibited a lower standard deviation than the comparative sample assemblies, indicating that the sample assemblies provided better consistency from part to part.

TABLE 19 Transmission loss of sample assemblies and comparative sample assemblies Transmission Loss (dB) Assembly 500 1,000 2,000 5,000 10,000 20,000 Example # Hz Hz Hz Hz Hz Hz 4a 25 25.90 26.80 26.90 26.70 26.90 27.20  13c 19.494 14.3307 10.87 4.33 2.0955 4.7469

TABLE 20 Phase of sample assemblies and comparative sample assemblies Phase (degrees) Assembly 500 1,000 2,000 5,000 10,000 20,000 Example # Hz Hz Hz Hz Hz Hz 4a 25 1.16 1.99 1.13 −2.62 −7.19 −14.31  13c −44.64 −64.00 −75.08 −83.62 −86.59 81.72

TABLE 21 Standard deviation of transmission loss of sample assemblies (n = 5) and comparative sample assemblies (n = 5) Standard Deviation of Transmission Loss (dB) Assembly 500 1,000 2,000 5,000 10,000 20,000 Example # Hz Hz Hz Hz Hz Hz 4a 25 1.05 0.92 0.82 0.76 0.67 0.61  13c 3.63 3.11 3.65 2.40 1.38 1.48

Example 5: Tunable Transmission Loss

For a given membrane, the transmission loss can be tuned via the support layer. You can use a support layer with a higher airflow to reduce TL and vice versa. Results are shown in FIG. 33.

TABLE 22 Transmission loss of sample assemblies Transmission Loss (dB) Assembly 500 1,000 2,000 5,000 10,000 20,000 Example # Hz Hz Hz Hz Hz Hz 5a 12 41.31 41.38 41.25 40.98 41.27 40.44 13 49.18 50.27 49.90 49.27 50.02 48.81

TABLE 23 Phase of sample assemblies Phase (degrees) Assembly 500 1,000 2,000 5,000 10,000 20,000 Example # Hz Hz Hz Hz Hz Hz 5a 12 1.82 0.75 1.60 1.38 0.40 1.40 13 3.33 2.18 −0.20 0.87 1.59 3.52

Examples 6 to 8—Further Non-Limiting Embodiments Exhibiting “Substantially Constant Acoustic Transmission” and “Resistive Behavior”

Preparation of Sample Assemblies

The following table (Table 24) outlines properties of exemplary membranes that are used in the foregoing examples. These properties are merely exemplary and not intended to be limiting.

TABLE 24 Properties of polymer membranes: Air Mass Max Flow Effective Young's per Bubble Pore Membrane Thickness Resistance Stiffness Modulus Area Point Size # (μm) (Rayls) (Pa/nm) (MPa) (g/m²) (psi) (μm) 10 13.3 12626 0.0053 29.60 3.74 30.1 0.4 11 0.6 1076 0.00165 50.04 0.1 15.4 0.8 12 8.2 3927 0.0076 27.70 1.3 17.4 0.7

Polymer membranes #10-12 above were prepared according to the following methods.

TABLE 25 Membrane preparation methods: Membrane # Preparation Method 10 Prepared according to the general teachings of U.S. Pat. No. 3,953,566 11 Prepared according to the general teachings of U.S. Pat. No. 3,953,566 & U.S. Pat. No. 7,306,729 12 Prepared according to the general teachings of U.S. Pat. No. 3,953,566

The following tables (Table 26A and Table 26B) outline properties of exemplary support structures that are used in the foregoing examples. These properties are merely exemplary and not intended to be limiting.

TABLE 26A Properties of support structures: Support Support Airflow Structure Structure Material Resistance # Type Composition (Rayls) 1 Network of Fluorinated ethylene propylene Not Measured particles (FEP) 2 Second Polymer Polytetrafluoroethylene 606.9 Membrane (PTFE) 3 Network of Fluorinated ethylene propylene Not Measured particles (FEP)

TABLE 26B Properties of support structures: Mass Support Effective per Structure % Open Thickness Area # Area % Contact (μm) (g/m²) 1 57.3 42.7 130.2 165.5 2 52.2 29.9 108 1.97 3 76.9 23.1 145 179.3

Support structures #1-3 above were prepared according to the following methods.

TABLE 27 Support structure preparation methods: Support Structure # Preparation Method 1 Prepared according to the general teachings of U.S. Pat. No. 8,808,848 2 Prepared according to the general teachings of U.S. Pat. No. 3,953,566 & U.S. Pat. No. 5,708,044 3 Prepared according to the general teachings of U.S. Pat. No. 8,808,848

Certain non-limiting sample assemblies and comparative sample assemblies described and tested herein were prepared as follows.

All example sample assemblies and comparative sample assemblies are comprised of at least one adhesive-backed fiberglass sample carrier, referred to as fiberglass sample carriers from this point forward. The fiberglass sample carriers were prepared by applying a double-sided pressure sensitive adhesive to one side of a fiberglass sheet (purchased commercially from McMaster-Carr, product #1331T37). The fiberglass sample carriers were then laser cut into coupons. A 1.5 mm diameter hole was then fabricated in the center that aligned with the inner bore of the impedance tube and corresponds to the active area of the sample to be measured. An exemplary stackup is shown in FIG. 34.

Sample Assemblies:

Sample Assemblies 35 & 37: Certain non-limiting sample assemblies (e.g. sample assemblies #35 and #37) were prepared using a coherent irregular network of NC1500 fluorinated ethylene propylene (FEP) thermoplastic particles (obtained commercially from Daikin, Japan) as support structure. Scanning electron micrographs of support structures #1 and #2 are shown in FIGS. 36 and 38, respectively. Support structures #1 and #3 were used in sample assemblies #35 and #37, respectively, and were prepared according to the methods in Table 27. Membranes #10 and #12 were used in sample assemblies #35 and #37, respectively, and were prepared according to the methods in Table 25. The final sample assemblies #35 and #37 were prepared as follows: A piece of the membrane with attached support structure was positioned on a smooth and level surface so that the membrane/support structure was flat and free of any wrinkles. The adhesive release liner was removed from a pre-cut fiberglass sample carrier to expose the adhesive. With adhesive layer exposed, the sample carrier was gently placed onto the support structure side and any excess material was cut away from the perimeter of the sample carrier. The sample carrier was then placed onto an alignment jig with membrane side facing up. The release liner was removed from a second fiberglass sample carrier and placed onto the alignment jig with adhesive side facing down, towards the membrane. Low pressure (manually applied and not measured) was applied to bring the bottom and top sample carriers together to form a sample assembly. The components and stack up of sample assemblies #35 and #37 are shown in Tables 28A and 28B.

Sample Assembly 36: Sample assembly #36 is comprised of a first polytetrafluoroethylene (PTFE) membrane (membrane #11) with a smaller pore size (tight layer) bonded to a second structure (support structure #2) in the form of a second (PTFE) membrane having a larger pore size (open layer) than the first PTFE membrane, and was prepared as follows. The first structure (membrane #11) having the smaller pore size was prepared according to the methods in Table 25. The second structure (support structure #2) was prepared according to the methods in Table 27. A scanning electron micrograph of support structures #2 is shown in FIG. 38. The Open-Tight PTFE composite membrane was prepared by placing an intermediate of the first structure process on the tape from the second structure process and then co-expanding the composite to obtain the sample assembly #36 including membrane #11 and support structure #2. A piece of the composite was positioned on a smooth and level surface so that the membrane/support structure composite was flat and free of any wrinkles. The adhesive release liner was removed from a pre-cut fiberglass sample carrier to expose the adhesive. With adhesive layer exposed, the sample carrier was gently placed onto the support side of the composite and any excess material was cut away from the perimeter of the sample carrier. The sample carrier was then placed onto an alignment jig with membrane side facing up. The release liner was removed from a second fiberglass sample carrier and placed onto the alignment jig with adhesive side facing down, towards the membrane. Low pressure (manually applied and not measured) was applied to bring the bottom and top sample carriers together to form a sample assembly. The components and stack up of sample assembly #36 is shown in Tables 28A and 28B.

TABLE 28A Exemplary configurations of sample assemblies: The following table lists the configuration of the assemblies used in the foregoing Examples. The “membrane #” and “support structure #” designated herein refer to Tables 24, 26A, and 26B respectively. Support No. of Assembly Structure Membrane Support # # # Structures 35 1 10 1 36 2 11 1 37 3 12 1

TABLE 28B Exemplary configurations of sample assemblies: The following table lists the configuration of the assemblies used in the foregoing Examples. The “membrane #” and “support structure #” designated herein refer to Tables 24, 26A, and 26B respectively. Assembly # Attachment Method Stackup 35 Thermal Deposition Fiberglass/adhesive/support structure/polymer membrane/adhesive/fiberglass 36 Co-Expansion Fiberglass/adhesive/support structure/polymer membrane/adhesive/fiberglass 37 Thermal Deposition Fiberglass/adhesive/support structure/polymer membrane/adhesive/fiberglass

A Scanning electron micrograph (SEM) showing a microstructure of support structure #1 bonded to membrane #10 is shown in FIG. 36.

A SEM showing a microstructure of support structure 2 is shown in FIG. 37.

A SEM showing a microstructure of support structure #3 attached to membrane #3 is shown in FIG. 38.

Comparative Sample Assemblies: Certain non-limiting comparative sample assemblies were prepared as follows: A piece of membrane was positioned on a smooth and level surface so that the membrane was flat and free of any wrinkled. The adhesive release liner was removed from a pre-cut fiberglass sample carrier to expose the adhesive. With adhesive layer exposed, the sample carrier was gently placed onto the membrane and any excess membrane was cut away from the perimeter of the sample carrier. The sample carrier was then placed onto an alignment jig with membrane side facing up. The release liner was removed from a second fiberglass sample carrier and placed onto the alignment jig with adhesive side facing down, towards the membrane. Low pressure (manually applied and not measured) was applied to bring the bottom and top sample carriers together to form a comparative sample assembly. The components and final stack up for comparative sample assemblies are shown in Tables 29A and 29B.

TABLE 29A Exemplary configurations of comparative sample assemblies: The following table lists the configuration of the comparative sample assemblies used in the foregoing examples. The “membrane #” and “support structure #” designated herein refer to Tables 24 and 26 respectively. Comparative Sample Support No. of Assembly Structure Membrane Support # # # Structures 18c None 10 0 19c None 11 0 20c None 12 0

TABLE 29B Exemplary configurations of comparative sample assemblies: The following table lists the configuration of the comparative sample assemblies used in the foregoing examples. The “membrane #” and “support structure #” designated herein refer to Tables 24 and 26 respectively. Comparative Sample Assembly Attachment # Method Stackup 18c Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 19c Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier 20c Unsupported Fiberglass sample carrier/polymer membrane/fiberglass sample carrier

Properties of Sample Assemblies and Comparative Sample Assemblies—The following table lists exemplary properties of certain sample assemblies and comparative sample assemblies. All properties are measured as described herein.

TABLE 30 Properties of certain sample assemblies: Pressure Difference Used for Airflow Sample Airflow Resistance Effective Assembly Resistance Test Stiffness # (Rayls) (psi) (Pa/nm) 35 3860 0.17 0.567 36 1683 0.17 0.0612 37 5408 0.17 1.712

TABLE 31 Properties of certain comparative sample assemblies: Pressure Difference Used for Comparative Airflow Sample Airflow Resistance Effective Assembly Resistance Test Stiffness # (Rayls) (psi) (Pa/nm) 18c 20711 0.17 0.0053 19c 1076 0.17 0.00165 20c 3927 0.17 0.0076

For all of the sample assemblies and comparative sample assemblies, transmission loss and phase angle testing was performed as described in Test Procedures section.

The transmission loss data for the sample assemblies and comparative sample assemblies of Examples 6-8 are shown in Table 32 at six discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, 15,000 Hz). The transmission loss vs. frequency spectra are shown in FIGS. 39 to 41.

TABLE 32 Transmission loss of Example #6, #7, #8 sample assemblies and comparative sample assemblies: Transmission Loss (dB) Example Assembly 500 1,000 2,000 5,000 10,000 15,000 # # Hz Hz Hz Hz Hz Hz 6 35 26.82 27.45 27.50 26.89 26.16 23.98  18c 18.91 15.17 10.35 3.83 1.09 1.282 7 36 7.44 6.54 5.22 3.25 2.92 2.66  19c 9.95 2.82 1.39 0.28 0.28 0.083 8 37 19.81 19.93 20.18 20.03 20.42 19.94  20c 11.97 8.91 6.00 2.11 1.11 0.361

The phase angle data of the Example #6, #7, #8 sample assemblies and comparative sample assemblies are shown in Table 33 at six discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, 15,000 Hz). The raw phase angle vs. frequency spectra of the tested sample assemblies are shown in FIGS. 39 to 41.

TABLE 33 Phase angle of sample assemblies & comparative sample assemblies of Examples 6-8: Phase Angle (degrees) Example Assembly 500 1,000 2,000 5,000 10,000 15,000 # # Hz Hz Hz Hz Hz Hz 6 35 2.9 −1.2 −3.4 −11.37 −27.56 −42.42  18c −58.2 −68.4 −71.6 −75.1 −31.6 28.62 7 36 −12.05 −25.05 −36.80 −46.66 −0.14 15.03  19c −58.74 −59.36 −68.37 −70.70 14.42 48.57 8 37 2.03 0.89 0.31 1.88 −4.45 −38.00  20c −41.56 −52.92 −66.96 −72.56 −78.69 −3.25

As shown, the above sample assemblies exhibit phase angles falling within the range of +45 degrees to −45 at the tested frequencies, while the comparative sample assemblies exhibit phase angles falling outside of the ranges of +45 degrees to −45 at some of the tested frequencies.

The slope of the transmission loss (in dB/Octave) for each sample assembly and for each comparative sample assembly was measured through a linear regression over the discrete frequencies (500 Hz, 1,000 Hz, 2,000 Hz, 5,000 Hz, 10,000 Hz, 15,000 Hz).

The frequencies were scaled to octaves using the following procedure:

The number of octaves between 500 Hz and 500 Hz is

${\log_{2}\left( \frac{500}{500} \right)} = 0$ The number of octaves between 500 Hz and 1000 Hz is

${\log_{2}\left( \frac{1000}{500} \right)} = 1$ The number of octaves between 500 Hz and 2000 Hz is

${\log_{2}\left( \frac{2000}{500} \right)} = 2$ The number of octaves between 500 Hz and 5000 Hz is

${\log_{2}\left( \frac{5000}{500} \right)} = 3.32$ The number of octaves between 500 Hz and 10,000 Hz is

${\log_{2}\left( \frac{10000}{500} \right)} = 4.32$ The number of octaves between 500 Hz and 15,000 Hz is

${\log_{2}\left( \frac{15000}{500} \right)} = 4.91$

The slope of the transmission loss spectrum of the sample assemblies and comparative sample assemblies can then be determined by performing a linear regression on the transmission loss data over the above-calculated octaves. The resulting slopes are shown in Table 34. For comparative sample assemblies, the transmission loss value will decrease with frequency in low frequency range and then increase with frequency in high frequency range. The linear regression is performed in the low frequency range for comparative sample assemblies. As shown in Table 34, for a given membrane, the slope of the transmission loss of sample assemblies was closer to zero than the slope the transmission loss of the comparative sample assemblies, indicating that the sample assemblies provided a more predominantly constant sound transmission profile. Specifically, as illustrated by the non-limiting examples below, in some embodiments of the present disclosure, the absolute value of the slope of transmission loss is 1.04 dB/octave or less (i.e., the transmission loss ranges from is −1.04 dB/octave to 0.06 dB/octave) over a 500 Hz to 15,000 Hz range. Put differently, in the non-limiting examples of Table 34, transmission loss does not vary by more than 1.04 dB/octave over the frequency range of 500 to 15,000 Hz.

TABLE 34 Slope of transmission loss of sample assemblies & comparative sample assemblies: Example Assembly Slope of TL (dB/Octave) over # # 500 Hz-15,000 Hz range 6 35 −0.491  18c −4.293 7 36 −1.039  19c −1.635 8 37 0.060  20c −2.405

The results of Tables 32-34 are also shown in FIGS. 39-41.

While several embodiments of the present disclosure have been described, these embodiments are illustrative only, and not restrictive, and that many modifications may become apparent to those of ordinary skill in the art. For example, all dimensions discussed herein are provided as examples only, and are intended to be illustrative and not restrictive. 

What is claimed is:
 1. An assembly comprising: a polymer membrane; and at least one support structure, wherein at least a portion of the at least one support structure is in contact with the polymer membrane; wherein the assembly has an airflow resistance of from 100 to 50,000 Rayls; wherein the assembly has an effective stiffness from 0.0002 Pa/nm to 3,000 Pa/nm when measured using a Vibrational Displacement Test (“VDT”); and wherein the assembly has an acoustic impedance with a phase angle of +45 degrees to −45 degrees over a frequency range of 50 to 20,000 Hz as measured by an Impedance Tube Transfer Matrix Test (“ITTMT”).
 2. The assembly of claim 1, wherein from 1% to 50% of the at least one support structure is in contact with the polymer membrane.
 3. The assembly of claim 1, wherein the assembly has a water entry pressure (“WEP”) ranging from 10 psi to 350 psi measured in accordance with a Capillary Piston Test (“CPT”).
 4. The assembly of claim 1, wherein the assembly exhibits a transmission loss of from 3 dB to 48 dB when measured by an Impedance Tube Transfer Matrix Test (“ITTMT”) over a frequency range of 50 to 20,000 Hz.
 5. The assembly of claim 1, wherein the assembly comprises a first support structure and a second support structure, wherein the polymer membrane is sandwiched between the first support structure and the second support structure; wherein the assembly comprises a first support structure and a second support structure, and wherein the polymer membrane is sandwiched between the first support structure and the second support structure.
 6. The assembly of claim 5, wherein the first and second support structures comprise a different material.
 7. An assembly, comprising: a polymer membrane; and at least one support structure, wherein at least a portion of the at least one support structure is in contact with the polymer membrane; wherein the assembly has an acoustic impedance with a phase angle of +45 degrees to −45 degrees over a frequency range of 50 to 20,000 Hz as measured by an Impedance Tube Transfer Matrix Test (“ITTMT”).
 8. The assembly of claim 7, wherein the polymer membrane has a thickness ranging from 0.025 microns to 300 microns.
 9. The assembly of claim 7, wherein the polymer membrane comprises a plurality of pores with different pore sizes, and wherein the plurality of pores has a maximum pore size ranging from 0.1 to 30 microns.
 10. The assembly of claim 9, wherein the support structure comprises a network of particles.
 11. The assembly of claim 7, wherein the polymer membrane has a bubble point ranging from 0.4 psi to 120 psi.
 12. The assembly of claim 7, wherein the at least one support structure is at least one second polymer membrane.
 13. The assembly of claim 7, wherein the at least one support structure has a thickness of 10 to 1000 microns.
 14. The assembly of claim 7, wherein the at least one support structure has an effective open area of from 5% to 98%.
 15. An assembly comprising: a polymer membrane; and at least one support structure, wherein at least a portion of the at least one support structure is in contact with the polymer membrane; wherein the assembly exhibits a transmission loss that does not vary by more than 1.5 dB/octave over a frequency range of 50 to 20,000 Hz when measured by an Impedance Tube Transfer Matrix Test (“ITTMT”).
 16. The assembly of claim 15, wherein the polymer membrane comprises expanded polytetrafluoroethylene (ePTFE).
 17. The assembly of claim 15, wherein the polymer membrane has a Young's Modulus ranging from 1 MPa to 1000 MPa.
 18. The assembly of claim 15, wherein the assembly comprises a single support structure.
 19. The assembly of claim 15, wherein the at least one support structure is at least one support layer, and wherein the at least one support layer comprises fiberglass.
 20. The assembly of claim 15, wherein the at least one support structure is at least one support layer, and wherein the at least one support layer comprises a metal. 